Horiuchi, Shinnosuke

写真a

Affiliation

Faculty of Science and Technology, Department of Chemistry ( Yagami )

Position

Associate Professor (Non-tenured)

E-mail Address

E-mail address

External Links
Scopus Paper Info  
Paper Count: 53 Citation Count: 1312 h-index: 19

Click to view the Scopus page. The data was downloaded from Scopus API in May 24, 2026, via http://api.elsevier.com and http://www.scopus.com .

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Career 【 Display / hide 】

  • 2010.04
    -
    2013.03

    The University of Tokyo, The Graduate School of Engineering, Department of Applied Chemistry, 日本学術振興会特別研究員(DC1)

  • 2013.01
    -
    2013.03

    University of Amsterdam, Van 't Hoff Institute for Molecular Sciences, Homogeneous, Supramolecular and Bio-Inspired Catalysis, Guest researcher

  • 2013.04
    -
    2015.03

    National Institutes of Natural Sciences, 協奏分子システム研究センター, IMSフェロー

  • 2015.04
    -
    2022.03

    Nagasaki University, Graduate school of Engineering, 助教

  • 2018.01
    -
    2018.11

    TU Dortmund University, The Faculty of Chemistry and Chemical Biology, Visiting researcher

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Academic Background 【 Display / hide 】

  • 2004.04
    -
    2008.03

    Tokyo Institute of Technology, School of Engineering, Dept. of Chemical Engineering

  • 2008.04
    -
    2010.03

    The University of Tokyo, The Graduate School of Engineering, Department of Applied Chemistry

  • 2010.04
    -
    2013.03

    The University of Tokyo, The Graduate School of Engineering, Department of Applied Chemistry

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Research Areas 【 Display / hide 】

  • Nanotechnology/Materials / Crystal engineering

  • Nanotechnology/Materials / Inorganic/coordination chemistry

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Research Keywords 【 Display / hide 】

  • 光化学

  • 放射光分光

  • 有機金属化学

  • 結晶学

  • 超分子化学

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Papers 【 Display / hide 】

  • Unveiling a host-guest assembly composed of an emissive Ir(III) complex salt and a concave aromatic host at a local minimum state

    Shota Ogura, Kanami Sugiyama, Masahiro Higashi, Shinnosuke Horiuchi

    Chemical Communications (Royal Society of Chemistry (RSC))  62   6577 - 6581 2026.03

    Last author, Corresponding author, Accepted,  ISSN  1359-7345

    　View Summary

    A host–guest complex formed at a local minimum state was isolated and characterized. Owing to solubility modulation induced by the formation of a supramolecular assembly, the host–guest complex at a...

  • Polymorphic imidoylamidinato platinum(II) complex that exhibits inverse symmetry breaking induced by both pressure and temperature

    Shinnosuke Horiuchi, Kenichiro Omoto, Ryo Kishikawa, Atsushi Fukuda, Toranosuke Matsuo, Hana Miyashita, Mayuka Fujiwara, Kenji Nakauchi, Hiroki Iida, Itaru Tsuchiya, Yoshiki Ozawa, Eri Sakuda, Kunihisa Sugimoto, Saori Kawaguchi, Hirokazu Kadobayashi, Shogo Kawaguchi, Yasuhiro Arikawa, Masaaki Abe, Keisuke Umakoshi

    ChemRxiv (American Chemical Society (ACS))   2026.02

    Lead author

  • Photophysical Modulation of an Elongated Ir(III) Complex by a Resorcin[4]arene Monomer Host

    Shota Ogura, Hiroki Uratani, Shinnosuke Horiuchi

    ChemPhotoChem (Wiley)  10 ( 1 ) e202500343 2025.12

    Last author, Corresponding author, Accepted,  ISSN  2367-0932

    　View Summary

    Molecular recognition of guest molecules within confined cavities enables effective modulation of their chemical and physical properties through noncovalent interactions. Because these modulated properties reflect the structural features of the host–guest assembly, the guest molecule can serve as a molecular probe to elucidate the origin of the host‐induced modulation. Herein, we report the formation of a host–guest complex composed of an emissive Ir(III) complex salt and a resorcin[4]arene host, along with the photophysical modulation of the guest via noncovalent interactions with the host. NMR spectroscopic analysis reveals a 1:1 binding stoichiometry, in contrast to the previously reported 6:1 stoichiometry, because the guest is larger than the cavity of the resorcin[4]arene hydrogen‐bonded hexameric capsule. This 1:1 binding mode is unambiguously confirmed by single‐crystal X‐ray diffraction analysis. The photoluminescent properties of the Ir(III) complex are enhanced in the presence of the host, indicating that electronic communication between the host and the guest plays a crucial role in modulating its photophysical behavior. These findings are further supported by density functional theory calculations. Overall, this article provides new insights into the photophysical dynamics of entrapped emitters and highlights the pivotal role of host–guest interactions in tuning emission properties.

  • Low-entropy supramolecular crystals elucidating the inhomogeneity of interfacial water molecules at atomic resolution

    Shinnosuke Horiuchi, Shota Ogura, Kazuya Otsubo, Yuka Ikemoto, Hisao Kiuchi, Yudai Shinozaki, Hiromi Tsuyuki, Go Watanabe, Osamu Takahashi, Mikihiro Hayashi, Eri Sakuda, Yasuhiro Arikawa, Keisuke Umakoshi, Yoshihisa Harada

    Nature Communications (Springer Science and Business Media LLC)  16 ( 1 ) 7588 2025.08

    Lead author, Corresponding author, Accepted

  • Anion‐Mediated Charge‐Transfer Assemblies Composed of Resorcin[4]Arene and Viologen Salts

    Yuki Konishi, Shinnosuke Horiuchi, Shota Ogura, Kanami Sugiyama, Hikaru Sotome, Mikihiro Hayashi, Masahiro Higashi, Tsukasa Abe, Shuichi Hiraoka

    Chemistry – A European Journal (Wiley)  31 ( 35 ) e202501042 2025.05

    Corresponding author, Accepted,  ISSN  0947-6539

    　View Summary

    Abstract

    Supramolecular assemblies of a concaved aromatic host as an electron donor (D) and a cationic heterocyclic guest as an electron acceptor (A) are reported. These molecular units were noncovalently bound to afford charge‐transfer (CT) complexes in solution and a CT cocrystal, displaying drastic color change from colorless to orange. The binding motif of the assemblies in the solution state was analyzed by NMR spectroscopic analysis and visualized by X‐ray crystallographic analysis. Theoretical calculations for the assemblies revealed electronic communication between the D and A fragments, proving their CT characteristics. The CT complexes were stabilized by not only CT and cation‐π interactions, but also Coulomb interaction between the cationic acceptor unit and its anion supported by a hydrogen bond with a hydroxy group in the aromatic host, resulted in enhancement of orbital overlapping of the D‐A fragments. Owing to the strong D‐A interaction in the assemblies, the CT complexes undergo ultrafast charge recombination on a femtosecond timescale after photoexcitation of the CT transition, as confirmed by transient absorption spectroscopy. These results demonstrate that understanding of assembly motif and its noncovalent interactions can lead to create optical materials manipulating electron transition dynamics.

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Reviews, Commentaries, etc. 【 Display / hide 】

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Presentations 【 Display / hide 】

  • Supramolecular crystals composed of coordination complexes and organic hosts

    Shinnosuke Horiuchi, Shota Ogura, Yuka Ikemoto, Osamu Takahashi, Yoshihisa Harada

    The 19th Conference of Asian Crystallographic Association 2025, 

    2025.12
    , 

    Oral presentation (invited, special)

  • Supramolecular Assemblies Composed of Luminescent Coordination Complexes and a Hydrogen-bonded Capsule

    Shinnosuke Horiuchi

    10th Asian Conference on Coordination Chemistry, 

    2025.10
    , 

    Oral presentation (invited, special)

  • Isolation and Characterization of a Metastable State through Solid-State-Driven Assembly

    Shota Ogura, Shinnosuke Horiuchi

    The 75th Conference of Japan Society of Coordination Chemistry, 

    2025.09
    , 

    Poster presentation

  • Solid State Assembly of Emissive Iridium Complexes and Organic Hosts

    Shota Ogura, Shinnosuke Horiuchi

    22nd Symposium on Host–Guest and Supramolecular Chemistry, 

    2025.06
    , 

    Poster presentation

  • Luminescent Coordination Complexes as a Molecular Probe in Supramolecular Organic-Inorganic Assemblies

    Shinnosuke Horiuchi

    245th ECS Meeting, 

    2024.05
    , 

    Oral presentation (general)

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Research Projects of Competitive Funds, etc. 【 Display / hide 】

  • 水素結合と分子間相互作用によって形成される有機無機複合体結晶の創成

    2023.04
    -
    2026.03

    日本学術振興会, 科学研究費助成事業 基盤研究(C), 基盤研究(C), Principal investigator

  • 遷移金属錯体を内包した複合体結晶の動的エキシトンの解明

    2023.04
    -
    2025.03

    日本学術振興会, 科学研究費助成事業 学術変革領域研究(A), 学術変革領域研究(A), Principal investigator

  • 分子間相互作用に基づく新奇細孔性材料の創出

    2022.10
    -
    2024.03

    公益財団法人 住友電工グループ社会貢献基金, Principal investigator

  • 水圏で形成される有機無機複合体結晶の創出と機能開拓

    2022.04
    -
    2024.03

    Japan Society for the Promotion of Science, Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area), Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area), No Setting

  • 細孔性複合体結晶の創出と1次元水チャネルの性状解明

    2021.10
    -
    2022.09

    公益財団法人 クリタ水・環境科学振興財団, 萌芽的研究, Principal investigator

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Awards 【 Display / hide 】

  • JSCC Research Encouragement Award 2023

    2023.09, Japan Society of Coordination Chemistry

  • 2019年度「貴金属に関わる研究助成金」奨励賞

    2020.04, 田中貴金属記念財団, 白金および貨幣金属を利用した発光性多核サンドイッチ錯体の創成

  • Best Paper Award

    2017.05, JSST2017, Development of Highly Emissive Host-Guest Complexes via Self-assembly and Encapsulation

  • 第61回討論会学生講演賞

    2011.10, 錯体化学会, Noncovalent Stabilization of Dinuclear Ruthenium-Carbonyl Complexes within a Self-assembled Hollow Cage

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Courses Taught 【 Display / hide 】

  • SEMINAR IN CHEMISTRY

    2026

  • LABORATORIES IN SCIENCE AND TECHNOLOGY

    2026

  • BACHELOR'S THESIS

    2026

  • LABORATORIES IN CHEMISTRY 2

    2026

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Media Coverage 【 Display / hide 】

  • Low‐Symmetry molecular assemblies formed through self‐assembly: A discovery by Nagasaki University, the University of Tokyo, and others

    JST, Science Japan (https://sj.jst.go.jp/news/202303/n0310-02k.html) , 2023.03

  • 分子間相互作用の協同効果を利用した低対称分子集合体の創出

    Chem-Station, スポットライトリサーチ (https://www.chem-station.com/blog/2023/02/hbss.html) , 2023.02

  • 超分子カプセル内包型発光性金属錯体の創製

    Chem-Station, スポットライトリサーチ (https://www.chem-station.com/blog/2016/10/coordinationcapsule%3A.html) , 2016.11

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