Papers - Matsumura, Shuichi

Enzymatic synthesis and crosslinking of high molecular weight polyepoxyricinoleate as novel thermosetting elastomers

Kazariya Ayaki, MATSUMURA SHUICHI

Polymers (MDPI)  4 ( 1 ) 486-500 2012.01

Research paper (scientific journal), Joint Work

グリーンポリマーの酵素合成

MATSUMURA SHUICHI

プラスチックス (日本プラスチック工業連盟)  62 ( 10 ) 20-26 2011.11

Research paper (scientific journal), Single Work

Enzymatic synthesis and properties of novel biodegradable and biobased thermoplastic elastomers

Kobayashi Takuma MATSUMURA SHUICHI

Polymer Degradation and Stability (Elsevier)  96 ( 11 ) 2071-2079 2011.11

Research paper (scientific journal), Joint Work, Accepted

Chemoenzymatic Synthesis and Chemical Recycling of Poly(ester-urethane)s

Hayashi Hiroto, Yanagishita Yoshio, MATSUMURA SHUICHI

International Journal of Molecular Sciences (MDPI Publishing, Basel, Switzerland)  12 ( 9 ) 5490-5507 2011.08

Research paper (scientific journal), Joint Work

Enzyme-Catalyzed Synthesis and Chemical Recycling of Aromatic Polyester via Cyclic Oligomer

Fukuda Shinya, MATSUMURA SHUICHI

高分子論文集 (高分子学会)  68 ( 5 ) 332-340 2011.05

Research paper (scientific journal), Joint Work, Accepted

Chemo-enzymatic synthesis and properties of novel optically active cationics containing carbonate linkages

Banno Taisuke, Kawada kazuo, MATSUMURA SHUICHI

Journal of Oleo Science (日本油化学会)  60 ( 4 ) 185-195 2011.03

Research paper (scientific journal), Joint Work, Accepted

Synthesis and properties of green sustainable carbonate-type nonionics containing polyoxyethylene chains

Banno Taisuke, Sato Hiroshi, Tsuda Takayuki, MATSUMURA SHUICHI

Journal of Oleo Science (日本油化学会)  60 ( 3 ) 117-126 2011.02

Research paper (scientific journal), Joint Work, Accepted

Enzymatic synthesis and chemical recycling of polythiocaprolactone

Shimokawa Keisuke, Kato Makoto, MATSUMURA SHUICHI

Macromolecular Chemistry and Physics (Wiley-VCH)  212 ( 2 ) 150-158 2011.01

Research paper (scientific journal), Joint Work, Accepted

Synthesis and enzymatic degradation of environmentally benign poly(carbonate/ester-urethane)s containing lactide oligomer

Murakami Saeko, Aoki Nobuyoshi, MATSUMURA SHUICHI

Transactions of the Materials Research Society of Japan (Materials Research Society of Japan)  35 ( 4 ) 805-808 2010.12

Research paper (scientific journal), Joint Work, Accepted

Enzymatic Preparation of Crosslinkable and Decrosslinkable Polyester with Pendant Mercapto Group

MATSUMURA SHUICHI

The 6th Keio LCC-Yonsei CBMH Joint Symposium  2010.10

Research paper (conference, symposium, etc.), Single Work

Creation of Novel Green and Sustainable Gemini-Type Cationics Containing Carbonate Linkages

Banno Taisuke, Kawada Kazuo, MATSUMURA SHUICHI

Journal of Surfactants and Detergents (Springer)  13 ( 4 ) 387-398 2010.09

Research paper (scientific journal), Joint Work, Accepted

　View Summary

Novel gemini-type cationics containing carbonate linkages as biodegradable and chemically recyclable segments were designed and synthesized by a green process. The carbonate linkages were introduced into only the hydrophobic moiety or in both the hydrophobic and linker moieties of gemini-type cationics. They showed higher surface activities, such as a low critical micelle concentration value, a surface tension lowering, and a high adsorption efficiency, when compared to the corresponding single-type cationics. Also, the gemini-type cationics containing carbonate linkages in both the hydrophobic and the linker moieties showed stronger antimicrobial activities when compared to those only in the hydrophobic moiety. It was found that some gemini-type cationics containing carbonate linkages showed higher biodegradability compared to the conventional gemini-type cationics. The biodegradability of the gemini-type cationics decreased when a carbonate linkage was introduced into the hydrophobic moiety rather than the linker moiety. However, some gemini-type cationics containing carbonate linkages both
in the hydrophobic and linker moieties showed ready biodegradability. The gemini-type cationics containing carbonate linkages in the hydrophobic moiety showed chemical recyclability by a lipase (E.C. 3.1.1.3).

Chemical recycling of poly(lactic acid)-based polymer blends using environmentally benign catalysts

Yota Tsuneizumi, Maiko Kuwahara, Kohei Okamoto, MATSUMURA SHUICHI

Polymer Degradation and Stability (Elsevier)  95 ( 8 ) 1387-1393 2010.08

Research paper (scientific journal), Joint Work, Accepted

High-Molecular-Weight Polycarbonate synthesized by Enzymatic Ring-Opening Polymerization of Cyclic Carbonate as a Green Process

YAMAMOTO YOSHIO, KAIHARA SACHIKO, TOSHIMA KAZUNOBU, MATSUMURA SHUICHI

Macromolecular Bioscience (Wiley-VCH)  9 ( 10 ) 968-978 2009.10

Research paper (scientific journal), Joint Work, Accepted

　View Summary

High-molecular-weight poly(tetramethylene carbonate) (PTeMC) and poly(hexamethylene carbonate) (PHMC) were prepared by the lipase-catalyzed polymerization of butane-1,4-diol or hexane-1,6-diol and diphenyl carbonate via the formation of a cyclic dimer by a green process. Cyclic carbonate dimers were prepared by the lipase-catalyzed condensation of diphenyl carbonate with butane-1,4-diol or hexane-1,6-diol in dilute toluene solution using an immobilized lipase from Candida antarctica, and was followed by the ring-opening polymerization of the cyclic dimer in bulk with the same lipase to produce PTeMC with Mw = 119000 g•mol-1 and PHMC with Mw = 399000 g•mol-1, respectively. Additionally, enzymatic polymerization of cyclic carbonate dimer was analyzed with respect to the Km and Vmax for the lipase.

Synthesis and Properties of Polycarboxylate-type Green Surfactants with S- or N-Linkages

OKADA YUU, BANNO TAISUKE,TOSHIMA KAZUNOBU,MATSUMURA SHUICHI

Journal of Oleo Science (日本油化学会)  58 ( 10 ) 519-528 2009.10

Research paper (scientific journal), Joint Work, Accepted

Synthesis and properties of green surfactants from renewable resources

MATSUMURA SHUICHI

5th Yonsei CBMH-Keio LCC Joint Symposium 2009 (Yonsei University, Korea)   2009.09

Research paper (other academic), Single Work

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Novel polycarboxylate-type anionic surfactants and gemini-type cationic surfactants having biodegradability and chemical recyclability were designed and synthesized as a green and sustainable surfactant. Their physicochemical properties, such as surfactant properties and calcium sequestration capacities, and biodegradability were evaluated.

酵素触媒重合法によるグリーンポリマーの創製

MATSUMURA SHUICHI

日本接着学会誌 (日本接着学会)  45 ( 8 ) 321-327 2009.08

Research paper (scientific journal), Single Work

Synthesis and Properties of Gemini-type Cationic Surfactants Containing Carbonate Linkages in the Linker Moiety Directed Toward Green and Sustainable Chemistry

Taisuke Banno, Kazunobu Toshima, Kazuo Kawada, MATSUMURA SHUICHI

Journal of Surfactants and Detergents (Springer)  12 ( 3 ) 249-259 2009.08

Research paper (scientific journal), Joint Work, Accepted

　View Summary

Gemini-type cationic surfactants containing
carbonate linkages as biodegradable and chemically recyclable
segments, consisting of two long-chain alkyl groups,
two quaternary ammonium groups and a linker moiety,
were designed and synthesized as novel green and sustainable
cationics with improved physicochemical and
biological activities. The gemini-type cationics containing
a carbonate linkage showed lower critical micelle concentration
values compared to the corresponding singletype
cationics. Also, the gemini-type cationics containing a
carbonate linkage in the linker moiety showed strong
antimicrobial activities. The biodegradability of the gemini-
type cationics was significantly improved when a carbonate
linkage was introduced into the linker moiety. The
maximum biochemical oxygen demand-biodegradability of
the gemini-type cationics containing a carbonate linkage in
the linker moiety exceeded 70% after a 28-day incubation.
Furthermore, the gemini-type cationics containing both a
carbonate linkage and an n-dodecyl group showed a
chemical recyclability using a lipase (E.C. 3.1.1.3).

Chemo-enzymatic synthesis of degradable PTMC-b-PECA-b-PTMC triblock copolymers and their micelle formation of pH-dependent controlled release

KAIHARA SACHIKO, JOHN P. FISHER, MATSUMURA SHUICHI

Macromolecular Bioscience (Wiley-VCH)  9 ( 6 ) 613-621 2009.06

Research paper (scientific journal), Joint Work, Accepted

　View Summary

一連の生体内分解性トリブロックコポリマーPTMC-b-PECA-b-PTMCを化学的方法と―リパーゼを用いた酵素合成により調製した。得られたブロックコポリマーについて種々のｐＨの緩衝液中での分解性の評価をおこなった。また非依存性コントロールリリーズのためのミセル形成能について検討を行った。

Cellular responses to degradable cyclic acetal modified PEG hydrogels

<Kaihara Sachiko, U>MATSUMURA SHUICHI(/)-#HR, Fisher, J. P.

Journal of Biomedical Materials Research, Part A 90 ( 3 ) 863-873 2009.03

Research paper (scientific journal), Joint Work, Accepted

Direct Enzymatic Synthesis of a Polyester with Free Pendant Mercapto Groups

Makoto Kato, Kazunobu Toshima,MATSUMURA SHUICHI

Biomacromolceules (American Chemical Society)  10 ( 2 ) 366-373 2009.02

Research paper (scientific journal), Joint Work, Accepted

2-フェニルキノリンーステロイドホルモンハイブリッド分子による標的タンパク選択的光分解と抗細胞活性

MATSUMURA SHUICHI

Chemical Biology (日本ケミカルバイオロジー学会)  2 ( 1 ) 1-4 2009.01

Research paper (scientific journal), Joint Work, Accepted

Target-selective photo-degradation of HIV-1 protease by a fullerene-sugar hybrid

S. Tanimoto, S. Sakai, S. Matsumura, D. Takahashi MATSUMURA SHUICHI K. Toshima

Chemical Communications (RSC Publishing)   ( 44 ) 5767-5769 2008.11

Research paper (scientific journal), Joint Work

Enzymatic synthesis and properties of green polyesters from renewable resources

MATSUMURA SHUICHI

The 4th Keio LCC- Yonsei CBMH joint symposium  2008.09

Research paper (conference, symposium, etc.), Single Work

Target-selective degradation of proteins by porphyrins upon visible photo-irradiation

S. Tanimoto MATSUMURA SHUICHI K. Toshima

Chemical Communications (RSC Publishing)   ( 31 ) 3678-3680 2008.08

Research paper (scientific journal), Joint Work, Accepted

　View Summary

A porphyrin derivative effectively and selectively degraded the target transcription factor, human estrogen receptor-alpha (hER-alpha), upon visible light irradiation, in the absence of additives and under neutral conditions.

Chemoselective reduction of Aldehydes over ketones with sodium tris(hexafluoroisopropoxy)borohydride

Y. Kuroiwa MATSUMURA SHUICHI K. Toshima

Synlett (Thieme)   ( 16 ) 2523-2525 2008.08

Research paper (scientific journal), Joint Work, Accepted

Preparation and Sustainable Chemical Recycling of Green Polyesters using Enzyme Catalysts

EBATA HIROKI, TOSHIMA KAZUNOBU,MATSUMURA SHUICHI

Journal of Synthetic Organic Chemistry (有機合成化学協会)  66 ( 7 ) 673-682 2008.07

Research paper (scientific journal), Joint Work, Accepted

　View Summary

Environmentally benign processes for polymer synthesis are needed in order to establish green and sustainable polymer chemistry. From the standpoint of saving natural resources and avoiding carbon dioxide emission, the use of renewable or biomass resources is essential for the production of such polymers. The application of enzymatic reactions for the production of green polymers may act as a key role for environmentally benign processes in the next generation. Furthermore, enzymes act effectively as catalysts for the chemical recycling of the polymers. This review focuses on enzymatic processes for polyester synthesis and chemical recycling of bio-based diol-diacid type polymers, poly(butylene succinate) and poly(butylene adipate), and hydroxy-acid type polymers, poly(ricinoleic acid) and poly(12-hydroxystearic acid). High-molecular-weight diol-diacid type polyesters are produced via the ring-opening polymerization of cyclic oligomers using lipase. The produced diol-diacid type polyesters are readily depolymerized by lipases foaming repolymerizable cyclic oligomers for chemical recycling. The sustainable chemical recycling of these polymers and polymer blends using an enzyme is also discussed.

Lipase-Catalyzed Ring-Opening Polymerization of Molecularly Pure Cyclic Oligomers for Use in Synthesis and Chemical Recycling of Aliphatic Polyesters

Kondo Asato, Sugihara Satoko, Kuwahara Maiko, Toshima Kazunobu, MATSUMURA SHUICHI

Macromolecular Bioscience (Wiley-VCH)  8 ( 6 ) 533-539 2008.06

Research paper (scientific journal), Joint Work, Accepted

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The lipase-catalyzed ROP of molecularly pure cyclic oligomers with a definite degree of oligomerization is analyzed with respect to the molecular weights of the resulting polymers and certain kinetic parameters of the enzymatic reaction. Cyclic BA dimers, trimers, and tetramers polymerize faster than the equivalent monomer; however, the latter produces PBA of significantly higher molecular weight. The reason is that the ring opening of the cyclic monomer is slow, leading to a lower initiator concentration than that produced by the cyclic BA dimer and trimer. Similarly, the cyclic BS dimer produces PBS of higher molecular weight than that obtained from the cyclic BS trimer.

環境にやさしい高分子合成法

Kato Makoto, MATSUMURA SHUICHI

高分子 (高分子学会)  57 ( 6 ) 438-441 2008.06

Research paper (scientific journal), Joint Work, Accepted

　View Summary

環境にやさしい高分子合成法の確立は持続的発展を遂げる上で必要不可欠な要素である。本稿では、発酵法や酵素触媒法など生物化学的なアプローチを中心とした高分子合成法、ケミカルリサイクル法、及び架橋やグラフトなどポリマーの修飾法について紹介する。これらバイオプロセスの活用は次世代の環境低負荷型高分子合成を担うことが期待される。

Lipase-catalyzed ring-opening polymerization of molecularly pure cyclic oligomers for use in synthesis and chemical recycling of aliphatic polyesters

A. Kondo, S. Sugihara, M. Kuwahara, K. Toshima MATSUMURA SHUICHI

Macromoleculalr Bioscience (Wiley-VCH)  8 ( 6 ) 533-539 2008.06

Research paper (scientific journal), Joint Work, Accepted

　View Summary

The cyclic oligomer is a key intermediate both for the lipase-catalyzed synthesis and chemical recycling of diol-diacid type polyesters, such as poly(butylene succinate) (PBS) and poly(butylene adipate) (PBA). The lipase-catalyzed ring-opening polymerization of molecularly pure cyclic oligomers with a definite oligomerization degree was analyzed with respect to the polymerization profiles, such as the molecular weight of the produced polymer and some kinetic parameters of the enzymatic reaction. The cyclic butylene adipate (BA) dimer to tetramer were polymerized faster than the cyclic BA monomer; however, the latter produced a significantly higher molecular weight PBA with an Mw 173000. Though the Kms for these cyclic oligomers were almost the same, the Vmax of the cyclic BA monomer was lower than those of the cyclic BA dimer and trimer. These results indicated that cyclic oligomers showed similar affinities with lipase, but the cyclic monomer tended to be slowly ring-opened by lipase forming the hydroxy acid type initiator. The instantaneous concentration of the hydroxy acid as an initiator was lower than that produced by the cyclic BA dimer and trimer, thus leading to the formation of a higher molecular weight polymer. Similarly, the cyclic BS dimer produced a higher molecular weight PBS with an Mw of 172000 when compared to the cyclic BS trimer.

Poly(ricinoleic acid) based novel thermosetting elastomer

Hiroki Ebata, Mayumi Yasuda, Kazunobu Toshima, MATSUMURA SHUICHI

Journal of Oleo Science (日本油化学会)  57 ( 6 ) 315-320 2008.06

Research paper (scientific journal), Joint Work, Accepted

　View Summary

A novel bio-based thermosetting elastomer was prepared by the lipase-catalyzed polymerization of methyl ricinoleate with subsequent vulcanization. Some mechanical properties of the cured carbon black-filled polyricinoleate compounds were evaluated as a thermosetting elastomer. It was found that the carbon black-filled polyricinoleate compounds were readily cured by sulfur curatives to produce a thermosetting elastomer that formed a rubber-like sheet with a smooth and non-sticky surface. The curing behaviors and mechanical properties were dependent on both the molecular weight of the polyricinoleate and the amount of the sulfur curatives. Cured compounds consisting of polyricinoleate with a molecular weight of 100,800 showed good mechanical properties, such as a hardness of 48 A based on the durometer A measurements, a tensile strength at break of 6.91 MPa and an elongation at break of 350 %.

Chemoenzymatic Synthesis and Chemical Recycling of Sustainable Polyurethanes

Yoshio Yanagishita, Makoto Kato, Kazunobu Toshima, and Shuichi Matsumura MATSUMURA SHUICHI

ChemSusChem (Wiley-VCH)  1 ( 1-2 ) 133-142 2008.02

Research paper (scientific journal), Joint Work, Accepted

　View Summary

Two novel types of chemically recyclable ester-containing polyurethanes, namely, a diol-diacid-type poly(diester-urethane) (PDEU) and a hydroxy acid type poly(ester-urethane) (PEU), were prepared by a green synthetic route that avoids the use of hazardous diisocyanate. The urethane linkage was introduced by the reaction of ethylene carbonate with amino alcohols and amino
acids to form urethanediol and urethane-containing hydroxy
acids, respectively. The urethanediol underwent polymerization with dimethyl adipate in the presence of lipase to produce a high-molecular-weight PDEU, while PEU was prepared by the lipase-catalyzed direct polycondensation of the urethane-containing
hydroxy acid monomer. The periodic introduction of ester
linkages into the polyurethane chain afforded primary biodegradation points and chemically recyclable segments. Both PDEU and PEU were readily degraded in the presence of lipase into oligomers which were readily repolymerized in the presence of the same enzyme.

Lipase-Catalyzed Synthesis and Properties of Poly(12-hydroxydodecanoate-co- 12-hydroxystearate) Directed Towards Novel Green and Sustainable Elastomer

Hiroki Ebata, Kazunobu Toshima, MATSUMURA SHUICHI

Macromolecular Bioscience (Wiley-VCH)  8 ( 1 ) 38-45 2008.01

Research paper (scientific journal), Joint Work, Accepted

Synthesis and characterization of cyclic acetal based degradable hydrogels

Sachiko Kaihara, MATSUMURA SHUICHI, John P. Fisher

Europian Journal of Pharmaceutical and Biopharmaceutics (Elsevier B. V.)  68 ( 1 ) 67-73 2008.01

Research paper (scientific journal), Joint Work, Accepted

　View Summary

The authers proposed to develop a hydrogel based on a cyclic acetal unit that produces diols and propanals upon hydrolytic degradation. In particular, the fabrication of hydrogels formed by the free radical polymerization of two diacrylate monomers, 5-ethyl-5-(hydroxymethyl)-b,b-dimethyl-1,3-dioxane-2-ethanol diacrylate (EHD), a cyclic acetal having two acryl groups, and poly(ethylene glycol)diacrylate(PEGDA) were proposed. This work develops a strategy to form hydrogels with a co-monomer system, one of which is hydrophobic, and subsequently describes the properties of the resulting hydrogel. Results showed that EH–PEG hydrogel may be formed using the co-solvent system. Further results indicated that swelling degree is dependent upon initiator concentration, monomer concentration, and molar ratios of monomers, while sol fraction significantly depended on initiator concentration and monomer concentration, only. These results demonstrate the ability to fabricate hydrogels using EHD and PEGDA system as well as to control the properties of the resulting hydrophilic networks.

Target selective degradation of prooteins by light-activated 2-phenylquinoline-estradiol hybrid

Akane Suzuki, Kana Tsumura, Takeo Tsuzuki, MATSUMURA SHUICHI, Kazunobu Toshima

Chemical Communications (RSC Publishing)  41   4260-4262 2007.11

Research paper (scientific journal), Joint Work, Accepted

　View Summary

a designed 2-phenylquinoline-estradiol hybrid effectively and selectively degraded the target transcription factor, human estrogen receptor-alpha, which has a high affinity with the estradiol moiety, under long-wavelength UV photo-irradiation, without additives and under neutral conditions.

Synthesis of poly(L-lactide) and polyglycolide by ring-opening polymerization

Sachiko Kaihara,MATSUMURA SHUICHI, Antonios G Mikos, John P Fisher

Nature Protocols 2 ( 11 ) 2767-2771 2007.11

Research paper (scientific journal), Joint Work, Accepted

Target-selective degradation of oligosaccharides by a light-activated small-molecule-lectin hybrid

Maiko Ishii, MATSUMURA SHUICHI, Kazunobu Toshima

Angewandte Chemie, International Edition (Wiley-VCH)  46   8396-8399 2007.10

Research paper (scientific journal), Joint Work

　View Summary

An innovative method for target-selective degradation of oligosaccharides induced by a light-activated hybrid molecule consisting of anthraquinone and lectin has been developed. The reaction takes place under neutral conditions, and no additives are required.

Synthesis and properties of poly[poly(ethylene glycol)-co-cyclic acetal]] based hydrogels

S. Kaihara, MATSUMURA SHUICHI,J. P. Fisher

Macromolecules (American Chemical Society)  40 ( 21 ) 7625-7632 2007.10

Research paper (scientific journal), Joint Work, Accepted

Toward the total synthesis of vineomycin B2: application of an efficient glycosylation methodology using 2,3-unsaturated sugards

Kaname Sasaki, MATSUMURA SHUICHI, Kazunobu Toshima

Tetrahedron Letters (Elsevier)  48 ( 39 ) 6982-6986 2007.09

Research paper (scientific journal), Joint Work, Accepted

　View Summary

The application of an efficient glycosylation methodology using 2,3-unsaturated sugards to synthesize critical precursors required for the total synthesis of an antibiotic, Vineomycin B2, was demonstrated.

Sulfated zirconia (SO4/ZrO2) as a reusable solid acid catalyst for the Mannich-type reaction between ketene silyl acetals and aldimines

Sainan Wang, MATSUMURA SHUICHI, Kazunobu Toshima

Tetrahedron Letters (Elsevier)  48 ( 37 ) 6449-6452 2007.09

Research paper (scientific journal), Joint Work, Accepted

　View Summary

Sulfated zirconia (SO4/ZrO2) catalyzed Mannich-type reaction of ketene silyl acetals and aldimines proceeded smoothly at room temperature to afford b-amino esters in good to high yields. In addition, the heterogeneous solid acid catalyst SO4/ZrO2 was easily recovered from the reaction mixture and then reused without significant loss of effectiveness.

Synthesis and Properties of Biodegradable and Chemically Recyclable Cationic Surfactants Containing Carbonate Linkages

Taisuke Banno, Kazunobu Toshima, Kazuo Kawada and MATSUMURA SHUICHI

Journal of Oleo Science (Japan Oil Chemists' Society)  56 ( 9 ) 493-499 2007.09

Research paper (scientific journal), Joint Work, Accepted

New strategy for controlling biodegradability of biodegradable polyesters by enzyme-catalyzed surface grafting

Hideto Tsuji, Misato Nishikawa, Yasushi Osanai,MATSUMURA SHUICHI

Macromolecular Rapid Communications (Wiley-VCH)  28   1651-1656 2007.08

Research paper (scientific journal), Joint Work, Accepted

Lipase-catalyzed synthesis and curing of high-molecular-weight polyricinoleate

Hiroki Ebata, Kazunobu Toshima, MATSUMURA SHUICHI

Macromolecular Bioscience (Wiley-VCH)  7 ( 6 ) 798-803 2007.06

Research paper (scientific journal), Joint Work, Accepted

　View Summary

High-molecular weight polyricinoleate having an Mw of 100,600 was enzymatically prepared by the polycondensation of methyl ricinoleate using immobilized lipase from Pseudomonas cepacia (IM-PC) in bulk in the presence of molecular sieves 4A at 80 ºC for 7 days. Polyricinoleate was a viscous liquid at room temperature having a glass transition temperature (Tg) of -74.8 ºC and showed no crystallinity, and biodegraded by activated sludge. Polyricinoleate was readily cured by a dicumyl peroxide at 170 ºC for 30 min to produce a chloroform-insoluble crosslinked polyricinoleate having a hardness of 50º using durometer A.

Synthesis and enzymatic degradation of environmentally benign poly(carbonate-urethane)

Murakami Saeko, Aoki Nobuyoshi, MATSUMURA SHUICHI

Transactions of the Materials Research Society of Japan 32 ( 4 ) 1211-1214 2007.04

Research paper (scientific journal), Joint Work, Accepted

Aryl C-glycosylation using an ionic liquid containing a protic acid

Chigusa Yamada, Kaname Sasaki, MATSUMURA SHUICHI, Kazunobu Toshima

Tetrahedron Letters (Elsevier)  48 ( 24 ) 4223-4227 2007.04

Research paper (scientific journal), Joint Work, Accepted

　View Summary

Aryl C-glycosylation of several glycosyl donors, including unprotected sugars, with phenol and naphthol derivatives in an ionic liquid containing a protic acid proceeded effectively and stereoselectively to give the corresponding aryl C-glycosides in good to high yields. Because the ionic liquid was nonvolatile, the reaction could be carried out under reduced pressure; in addition, the ionic liquid could be reused without loss of effectivelness. The features contribute to the significant advantages of this novel aryl C-glycosylation reaction.

Synthesis and enzymatic degradation of environmentally benign poly(carbonate-urethane)

Saeko Murakami, Nobuyoshi Aoki, MATSUMURA SHUICHI

Transactions of the Materials Research Society of Japan 32 ( 4 ) 1211-1214 2007

Research paper (scientific journal), Joint Work, Accepted

An efficient glycosidation method using 2,3-unsaturated glycosyl donors

Kaname Sasaki, MATSUMURA SHUICHI, Kazunobu Toshima

Tetrahedron Letters (Elsevier)  47   9039-9043 2006.11

Research paper (scientific journal), Joint Work, Accepted

Synthesis of hexopyranosyl acetates and 2,3-disubstituted tetrahydropyrans via chemoselective hydrogenation of hex-2-enopyranosyl acetates

MATSUMURA SHUICHIKaname Sasaki, Takayuki Wakamatsu, Kazunobu Toshima

Tetrahedron Letters (Elsevier)  47   8271-8274 2006.10

Research paper (scientific journal), Single Work, Accepted

研究室紹介

MATSUMURA SHUICHI

オレオサイエンス (日本油化学会)  6 ( 10 ) 545 2006.10

Research paper (scientific journal), Single Work

The use of organophotoacids for deprotection reactions in organic synthesis

MATSUMURA SHUICHIYuichi Nishikubo, Shinya Kanzaki, Kazunobu Toshima

Tetrahedron Letters (Elsevier)  47 ( 46 ) 8125-8128 2006.09

Research paper (scientific journal), Joint Work

Enzyme-catalyzed synthesis and degradation of polyester and polythioester

MATSUMURA SHUICHI, Kato Makoto, Sugihara Satoko, Toshima Kazunobu

Polymer Preprints (American Chemical Society)  47 ( 2 ) 239-240 2006.09

Research paper (scientific journal), Joint Work, Accepted

　View Summary

Enzyme-catalyzed synthesis and degradation of a typical diol-diacid type plastic, poly(butylene succinate) (PBS), and diol-diacid type polythioester were studied with respect to the establishment of sustainable polymer production and chemical recycling system. A significantly higher-molecular weight polyester was produced via the ring-opening polymerization of the cyclic oligomer. The cyclic oligomer was produced both by the condensation of monomers and degradation of the polyester. Polymer blends of PBS/poly(L-lactic acid) (PLLA) were degraded into repolymerizable oligomers, first by the lipase-catalyzed degradation of PBS into cyclic BS oligomers followed by the degradation of PLLA into lactic acid oligomers by montmorillonite K-5. By the reprecipitation procedures, the PLLA and BS oligomers were completely separated. Aliphatic dithiol-diacid type polythioesters were enzymatically prepared by the direct polycondensation of dithiol and diacid diesters. A higher molecular weight polythioester was produced using lipase in a two-step procedure, i.e., cyclization with subsequent ring-opening polymerization.

Enzyme-catalyzed preparation of aliphatic polythioester by direct polycondensation of diacid diester and dithiol

Makoto Kato, Kazunobu Toshima, MATSUMURA SHUICHI

Macromolecular Rapid Communications (Wiley-VCH)  27 ( 8 ) 605-610 2006.05

Research paper (scientific journal), Joint Work, Accepted

　View Summary

Aliphatic dithiol-diacid type polyethioester were first enzymatically prepared by the direct polycondensation of hexane-1,6-dithiol and diacid diesters using the immobilized lipase from Candida antarctica (lipase CA). Both the melting and crystallization temperatures of the produced polythioesters were higher when compared to those of the corresponding polyoxyesters.

Enzymatic transformation of aliphatic polyesters into cyclic oligomers using enzyme packed column under continuous flow of supercritical carbon dioxide with toluene

Osanai Shuichi, Toshima Kazunobu,MATSUMURA SHUICHI,

Science and Technology of Advanced Materials (Elsevier)  7 ( 2 ) 202-208 2006.04

Research paper (scientific journal), Joint Work, Accepted

　View Summary

The enzymatic degradation of chemically synthesized typical biodegradable plastics, such as poly(R,S-3-hydroxybutanoate), poly(-caprolactone) and poly(butylene adipate), into reactive cyclic oligomers under the continuous flow of supercritical or subcritical carbon dioxide (scCO2) with toluene through an enzyme column was studied with reference to chemical recycling. It was confirmed that all the tested polymers were quantitatively transformed into the corresponding cyclic oligomers by passage through the column packed with immobilized lipase from Candida antarctica (Novozym 435) at 40 ℃ under the continuous flow of scCO2 with some organic solvent. Compared to the pure organic solvents, by the addition of scCO2 as a mobile phase degradation of the polymer was significantly promoted with respect to the reaction time, temperature and polymer concentration for complete transformation of the polyesters into oligomers through the enzyme column.

Molecular design, chemical synthesis, and evaluation of novel anthracene derivatives as a new fammily of protein photocleavers

Masashi Hasegawa, Akane suzuki,MATSUMURA SHUICHI, Kazunobu Toshima

Science and Technology of Advanced Materials (Elsevier)  7 ( 2 ) 169-174 2006.03

Research paper (scientific journal), Joint Work, Accepted

　View Summary

The newly designed and synthesized artificial anthracene derivatives possessing a deoxyamino sugar effectively and randomly cleaved proteins, such as bovine serum albumin (BSA) and hen egg lysozyme (Lyso), during photoirradiation using a long wavelength UV light (365 nm) without any further additives. Furthermore, it was found that the cleaving ability of anthracene could be improved by the attachment of a suitable substitute into anthracene core skeleton.

Perspectives for synthesis and production of polyurethanes and related polymers by enzymes directed toward green and sustainable chemistry

MATSUMURA SHUICHI, Soeda Yasuyuki, Toshima Kazunobu

Applied Microbiology and Biotechnology (Springer-Verlag)  70 ( 1 ) 12-20 2006.03

Research paper (scientific journal), Joint Work, Accepted

One-step syntheses of alkyl glycosides and alkyl-substituted DNA oligomers by chemoselective glycosidations using DNA bases

Nishikubo Y, Sasaki K, MATSUMURA SHUICHI, Toshima K

Tetrahedron Letters (Elsevier)  47 ( 7 ) 1041-1045 2006.02

Research paper (scientific journal), Joint Work, Accepted

New strategy for enzymatic synthesis of high-molecular-weight poly(butylene succinate) via cyclic oligomers

Sugihara Satoko, Tosima Kazunobu, MATSUMURA SHUICHI

Macromolecular Rapid Communications (Wiley-VCH)  27 ( 3 ) 203-207 2006.02

Research paper (scientific journal), Joint Work, Accepted

Deprotection of benzyl ethers using 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) under photoirradiation

Mohammad Abdur Rahim, MATSUMURA SHUICHI, Kazunobu Toshima

Tetrahedron Letters (Elsevier)  46 ( 43 ) 7307-7309 2005.10

Research paper (scientific journal), Single Work, Accepted

グリーンポリマーの合成とケミカルリサイクル

MATSUMURA SHUICHI

ケミカルエンジニャリング 50 ( 10 ) 771-778 2005.10

Research paper (scientific journal), Single Work

Deprotection of benzyl ethers using 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) under photoirradiation

MATSUMURA SHUICHIMohammad Abdur Rahim, Kazunobu Toshima

Tetrahedron Letters (Elsevier)  46   7307-7309 2005.09

Research paper (scientific journal), Joint Work, Accepted

Degradation of poly(lactic acid) into repolymerizable oligomer using montmorillonite K10 for chemical recycling

Kohei Okamoto, Kazunobu Toshima, MATSUMURA SHUICHI

Macromolecular Bioscience (Wiley-VCH)  5 ( 9 ) 813-820 2005.09

Research paper (scientific journal), Joint Work, Accepted

Anthraquinone derivatives as a new family of protein photocleaves

MATSUMURA SHUICHIA. Suzuki, M. Hasegawa, M. Ishii, K. Toshima

Bioorganic & Medicinal Chemistry Letters 15   4624-4627 2005.08

Research paper (scientific journal), Single Work, Accepted

シリーズ：グリーンポリマーの研究開発動向５ 酵素法によるグリーンポリマーのリサイクル

MATSUMURA SHUICHI

バイオサイエンスとインダストリー (バイオインダストリー協会)  63 ( 8 ) 48-51 2005.08

Research paper (scientific journal), Single Work

Molecular design, chemical synthesis, and evaluation of cytosine-carbohydrate hybrids for selective recognition of a single guanine bulged duplex DNA

MATSUMURA SHUICHI, Yusuke Idutsu, Ayaka Sasaki, Kazunobu Toshima

Bioorganic & Medicinal Chemistry Letters 15   4332-4335 2005.08

Research paper (scientific journal), Joint Work, Accepted

Enzymatic transformation of bacterial polyhydroxyalkanoates into repolymerizable oligomers directed towards chemical recycling

Sachiko Kaihara, Yasushi Osania, Kimihito Nishikawa, Kazunobu Toshima, MATSUMURA SHUICHI

Macromolecular Bioscience (Wiley-VCH)  5 ( 7 ) 644-652 2005.07

Research paper (scientific journal), Joint Work

酵素法によるグリーンプラスチックの創成

MATSUMURA SHUICHI

月刊バイオインダストリー (シーエムシー出版)  22 ( 7 ) 51-60 2005.07

Research paper (scientific journal), Single Work

固体酸を用いるポリ乳酸のケミカルリサイクル

MATSUMURA SHUICHI, Okamoto Kohei, Toshima Kazunobu

月刊ファインケミカル (シーエムシー出版)  34 ( 8 ) 20-28 2005.07

Research paper (scientific journal), Joint Work

Preparation of aliphatic poly(thioester) by the lipase-catalyzed direct polycondensation of 11-mercaptoundecanoic acid

Makoto Kato, Kazunobu Toshima, MATSUMURA SHUICHI,

Biomacromolecules 6 ( 4 ) 2275-2280 2005.07

Research paper (scientific journal), Joint Work, Accepted

酵素法によるグリーンプラスチックの創成

MATSUMURA SHUICHI

BIO INDUTRRY（バイオインダストリー） 22 ( 7 ) 51-60 2005.06

Research paper (scientific journal), Single Work,  ISSN  0910-6545

Synthesis and chemical recycling of novel poly(ester-urethane)s using an enzyme

Soeda Yasuyuki, Toshima Kazunobu,　MATSUMURA SHUICHI

Macromolecular Bioscience (Wiley-VCH)  5 ( 4 ) 277-288 2005.04

Research paper (scientific journal), Joint Work, Accepted

次世代型グリーンポリウレタンー酵素触媒による生分解性ポリ（カーボネートーウレタン）およびポリ（エステルーウレタン）の合成とケミカルリサイクル

Soeda Yasuyuki, Toshima Kazunobu, MATSUMURA SHUICHI

高分子加工 (高分子加工刊行会)  54 ( 3 ) 127-133 2005.03

Research paper (scientific journal), Joint Work

Environmentally benign b-stereoselective glycosidations of glycosyl phosphites using a reusable heterogeneous solid acid, montmorillonite K-10

MATSUMURA SHUICHI, Nagai Hideki, Sasaki Kaname, Toshima Kazunobu

Carbohydrate Research 340 ( 340 ) 337-353 2005.03

Research paper (scientific journal), Joint Work

循環型ケミカルリサイクルのための超臨界二酸化炭素及び酵素カラムを用いた生分解性脂肪族ポリエステルの環状オリゴマー化

MATSUMURA SHUICHI, Osanai Yasushi

JASCOレポート  ( 8 ) 5-9 2004.11

Research paper (other academic), Joint Work,  ISSN  0916-3492

Synthetic studies on apoptolidin: synthesis of the C12-C28 fragment via a highly stereoselective aldol reaction

MATSUMURA SHUICHI

Tetrahedron Letters 45 ( 48 ) 8849-8853 2004.11

Research paper (scientific journal), Joint Work, Accepted

Transformation of Biodegradable Polyesters into Cyclic Oligomers under Continuous Flow Using an Enzyme-Packed Column

Osanai Yasushi, Toshima Kazunobu, MATSUMURA SHUICHI

Macromolecular Bioscience (Wiley-VCH)  4 ( 10 ) 936-942 2004.10

Research paper (scientific journal), Joint Work, Accepted

A novel glycosidation of glycosyl fluoride using a designed ionic liquid and its effect on the stereoselectivityTee

MATSUMURA SHUICHI

Tetrahedron Letters 45 ( 38 ) 7043-7047 2004.09

Research paper (scientific journal), Joint Work, Accepted

Enzymatic Synthesis and Chemical Recycling of Poly(carbonate-urethane)

Soeda Yasuyuki, Toshima Kazunobu, MATSUMURA SHUICHI

Macromolecular Bioscience (Wiley-VCH)  4 ( 8 ) 721-728 2004.08

Research paper (scientific journal), Joint Work, Accepted

循環型高分子としてのグリーンプラ：循環型ケミカルリサイクルへの道

MATSUMURA SHUICHI

グリーンプラジャーナル  ( 14 ) 14-17 2004.07

Research paper (scientific journal), Single Work

The significant effect of the carbohydrate structures on the DNA photocleavage of the quinoxaline-carbohydrate hybrids

MATSUMURA SHUICHI

Bioorganic & Medicinal Chemistry Letters 14 ( 11 ) 2777-2779 2004.06

Research paper (scientific journal), Joint Work

Stereocontrolled glycosidations using a heterogeneous solid acid, sulfated zirconia, for the direct synthesis of a- and b-manno- and 2-deoxyglucopyranosides

MATSUMURA SHUICHI K. Toshima, H. Nagai, K. Kasumi, K. Kawahara, S. Matsumura

Tetrahedron 60 ( 25 ) 5331-5339 2004.06

Research paper (scientific journal), Single Work, Accepted

Molecular design, chemical synthesis and biological evaluation of anthracene-carbohydrate hybrids as novel DNA photocleaving and photoselective cytotoxic agents

MATSUMURA SHUICHI K. Toshima, M. Hasegawa, J. Shimizu

ARKIVOC 2004 ( 1 ) 28-35 2004.05

Research paper (scientific journal), Joint Work

Lipase-Catalyzed Transformation of Poly(lactic acid) into Cyclic Oligomer

Y. Takahashi, S. Okajima, K. Toshima, MATSUMURA SHUICHI

Macromolecular Bioscience (wiley-VCH)  4 ( 3 ) 346-353 2004.03

Research paper (scientific journal), Single Work

Novel anthraquinone-carbhydrate hybrids: The significant improvement of the DNA photocleaving activity and the cytotoxic selectivity

MATSUMURA SHUICHI K. Toshima, Y. Nakajima, Y. Maeda,

Letters in Organic Chemistry 1 ( 1 ) 31-33 2004

Research paper (scientific journal), Joint Work, Accepted

Lipase-Catalyzed Transformation of Poly(butylene adipate) and Poly(butylene succinate) into Repolymerizable Cyclic Oligomers

S. Okajima, R. Kondo, K. Toshima, MATSUMURA SHUICHI

Biomacromolecules (ACS)  4 ( 6 ) 1514-1519 2003.12

Research paper (scientific journal), Single Work, Accepted

Enzymatic Synthesis of Surface Active and Biodegradable Glucosaminide Fatty Acid Esters

Sagoh Tooru, Toshima Kazunobu, Kawada Kazuo, MATSUMURA SHUICHI

Journal of Oleo Science (日本油化学会)  52 ( 11 ) 597-606 2003.11

Research paper (scientific journal), Joint Work, Accepted

Molecular design, chemical synthesis, and biological evaluation of novel anthraquinone-carbohydrate hybrids as photo-induced DNA cleaving and cytotoxic agents

MATSUMURA SHUICHITOSHIMA KAZUNOBU, YOKO NAKAJIMA

Trends in Organic Chemistry 10 ( 10 ) 113-117 2003.10

Research paper (scientific journal), Joint Work

Enzymatic Degradation of Poly(3-hydroxybutyrate) to Cyclic Oligomers under Continuous Flow

Osanai Yasushi, Toshima Kazunobu, MATSUMURA SHUICHI

Green Chemistry (The Royal Society of Chemistry)  5 ( 5 ) 567-570 2003.10

Research paper (scientific journal), Joint Work

Thermal and Infrared Spectroscopic Studies on Hydrogen-Bonding Interaction of Biodegradable Poly(3-hydroxybutyrate)s with Natural Polyphenol Catechin

B. Zhu, J. Li, Y. He, Y. Osanai, MATSUMURA SHUICHI Y. Inoue

Green Chemistry (The Royal Society of Chemistry)  5 ( 5 ) 580-586 2003.10

Research paper (scientific journal), Single Work, Accepted

Correlation between structure of the lactones and substrate specificity in enzyme-catalyzed polymerization for the synthesis of polyesters

Suzuki Yoichi, Taguchi Seiichi, Hisano Tamao, Toshima, Kazunobu, MATSUMURA SHUICHI, Doi Yoshiharu

Biomacromolecules (ACS)  4 ( 3 ) 537-543 2003.09

Research paper (scientific journal), Joint Work, Accepted

Enzymatic Synthesis and Polymerization of Cyclic Trimethylene Carbonate Monomer With/without Methyl Substituent

H. Tasaki, K. Toshima, MATSUMURA SHUICHI

Macromolecular Bioscience 3 ( 8 ) 436-441 2003.08

Research paper (scientific journal), Single Work, Accepted

グリーンポリマーの技術動向と酵素法によるケミカルリサイクル

MATSUMURA SHUICHI

グリーンケミストリー調査研究委員会講演会 (グリーンケミストリー調査研究委員会)   2003.07

Research paper (conference, symposium, etc.), Single Work

ポリアスパラギン酸の酵素合成と生分解性

Soeda Yasuyuki, Otozawa Nobuyuki, Toshima Kazunobu, MATSUMURA SHUICHI

高分子加工 (㈱高分子刊行会)  52 ( 7 ) 323-332 2003.07

Research paper (scientific journal), Joint Work

Sustainable enzymatic preparation of polyaspartate using a bacterial protease

Soeda Yasuyuki, Toshima Kazunobu, MATSUMURA SHUICHI

Biomacromolecules (ACS)  4 ( 2 ) 196-203 2003.04

Research paper (scientific journal), Single Work, Accepted

Phase-separation enhanced enzymatic degradation of atactic poly(3-hydroxybutyrate) in the blends with poly(methyl methacrylate)

Y.-H. Na, Y. He, T. Nishiwaki, Y. Inagawa, Y. Osanai, MATSUMURA SHUICHI, T. Saito, Y. Doi, Y. Inoue

Polymer Degradation and Stability (Elsevier)  79 ( 3 ) 535-545 2003.03

Research paper (scientific journal), Joint Work, Accepted

Enzyme-catalyzed preparation of aliphatic polyesters containing thioester linkages

Iwata Shin, Toshima Kazunobu, MATSUMURA SHUICHI

Macromolecular Rapid Communications (Wiley-VCH)  24 ( 7 ) 467-471 2003.03

Research paper (scientific journal), Joint Work, Accepted

酵素法によるグリーンポリマーの合成とケミカルリサイクル

MATSUMURA SHUICHI

環境工学連合講演会講演論文集 (日本学術会議)     117-124 2003.02

Research paper (conference, symposium, etc.), Single Work

Novel anthraquinone-carbohydrate hybrids: The significant improvement of the DNA photocleaving activity and the cytotoxic selectivity

MATSUMURA SHUICHI K. Toshima, Y. Nakajima, Y. Maeda, S. Matsumura

Letters in Organic Chemistry 1 ( 1 ) 31-33 2003.01

Research paper (scientific journal), Single Work

生分解性界面活性剤の最新動向

MATSUMURA SHUICHI

エコインダストリー (シーエムシー)  8 ( 1 ) 12-23 2003.01

Research paper (scientific journal), Single Work

Glycidol-carbohydrate hybrids: A new family of DNA alkylating agents

MATSUMURA SHUICHI K. Toshima, Y. Okuno, S. Matsumura

Bioorganic & Medicinal Chemistry Letters 13   3281-3283 2003

Research paper (scientific journal), Single Work

Environmentally benign and stereoselective formation of b-mannosidic linkages utilizing 2,3-di-O-benzyl-4,6-O-benzylidene-protected mannopyranosyl phosphite and montmorillonite K-10

MATSUMURA SHUICHI H. Nagai, S. Matsumura, K. Toshima

Carbohydrate Research 338 ( 15 ) 1531-1534 2003

Research paper (scientific journal), Single Work

Molecular design, chemical synthesis and biological evaluation of quinaxaline-carbohydrate hybrids as novel and selective photo-induced DNA cleaving and cytotoxic agents

MATSUMURA SHUICHI K. Toshima, T. Kimura, R. Takano, T. Ozawa, A. Ariga, Y. Shima, K. Umezawa, S. Matsumura

Tetrahedron 59   7057-7066 2003

Research paper (scientific journal), Single Work

A novel greener glycosidation using an acid-ionic liquid containing a protic acid

MATSUMURA SHUICHI K. Sasaki, H. Nagai, S. Matsumura, K. Toshima,

Tetrahedron Letters 44 ( 30 ) 5605-5608 2003

Research paper (scientific journal), Single Work

Vacuolar-type H+ -ATPase inhibitory activity of synthetic analogues of the concanamycins: Is the hydrogen bond network involving the lactone carbonyl, the hemiacetal hydroxy group, and the C-19 hydroxy group essential for the biological activity of the concanamycins?

MATSUMURA SHUICHI Toshima K et al.

BIOORGANIC & MEDICINAL CHEMISTRY LETTERS 12 ( 24 ) 3525-3528 2002.12

Research paper (scientific journal), Joint Work

Enzymatic ring-opening polymerization of oxiranes and dicarboxylic anhydrides

Soeda Yasuyuki, Okamoto Ttakeshi, Toshima Kazunobu, MATSUMURA SHUICHI

Macromolecular Bioscience (Wiley-VCH)  2 ( 9 ) 429-436 2002.12

Research paper (scientific journal), Joint Work, Accepted

Environmentally benign and stereoselective construction of 2-deoxy and 2,6-dideoxy-beta-glycosidic linkages employing 2-deoxy and 2,6-dideoxyglycosyl phosphites and montmorillonite K-10

MATSUMURA SHUICHI Nagai H, Toshima K

Chemistry Letters 2002 ( 11 ) 1100-1101 2002.11

Research paper (scientific journal), Joint Work

酵素触媒重合によるオキシランの開環重合

Soeda Yasuyuki, Toshima Kazunobu, MATSUMURA SHUICHI

高分子加工 (高分子刊行会)  51 ( 10 ) 435-442 2002.10

Research paper (scientific journal), Joint Work

Enzymatic hydrolysis of chemosynthesized atactic poly(3-hydroxybutyrate) by poly(3-hydroxybutylate) depolymerase from Acidovorax sp. TP4 and Ralstonia pickettii Ti

Wang Yi, Inagawa Yasuhide, Osanai Yasushi, Kasuya Ken-ichi, Saito Terumi, Matsumura Shuichi, Doi Yoshiharu, Inoue YoshioMATSUMURA SHUICHI

Biomacromollecules (ACS)  3 ( 5 ) 894-898 2002.10

Research paper (scientific journal), Joint Work, Accepted

酵素触媒重合と分解プロセスを活用する循環型グリーンポリマーの創製

MATSUMURA SHUICHI

繊維学会誌 (繊維学会)  58 ( 4 ) P-94 - P98 2002.04

Research paper (scientific journal), Single Work

酵素リパーゼを利用したプラスチックリサイクル

工業技術、50    97-100 2002.03

Research paper (scientific journal), Single Work

Lipase-catalyzed Transformation of Unnatural Type P(3HB) into Reactive Cyclic Oligomer as Chemical Recycling

Y. Osanai, N. Yoshie, Y. Inoue, K. Toshima, S. Matsumura

Macromolecular Bioscience 2 ( 2 ) 88-94 2002.03

Research paper (scientific journal), Joint Work

酵素を用いる循環型プラスチックリサイクル法

MATERIAL STAGE, 1    43-47 2002.02

Single Work

A Highly Stereoselective Synthesis of β-Olivosides by Glycosidations of 2-Iodo-olivosyl Fluoride Using Montmorillonite K-10 as an Environmentally Benign Solid Acid

K. Uehara, H. Nagai, S. Matsumura, K. Toshima

Green Chemistry, 4    27-29 2002.02

Joint Work

Molecular Design and Evaluation of Quinoxaline-Carbohydrate Hybrids as Novel and Efficient Photo-Induced GG-Selective DNA Cleaving Agents

R. Takano, T. Ozawa, S. Matsumura, K. Toshima

Chemical Communications    212-213 2002.02

Joint Work

β-Carboline-Carbohydrate Hybrids: Molecular Design, Chemical Synthesis and Evaluation of Novel DNA Photocleavers

Y. Okuno, Y. Nakajima, S. Matsumura, K. Toshima

Bioorganic & Medicinal Chemistry Letters, 12    671-673 2002.02

Joint Work

Polymeric Antioxidants. V. Ortho methylene-bridged and direct-linked sesamol oligomers

K. Asakura, E. Honda, S. Matsumura, S. Osanai, K. Kawada

Journal of Oleo Science (日本油化学会)  51 ( 2 ) 97-102 2002.02

Research paper (scientific journal), Joint Work, Accepted

Enzyme-catalyzed synthesis and chemical recycling of polyesters

Matsumura Shuichi

Macromolecular Bioscience (Wiley-VCH)  2 ( 3 ) 105-126 2002.02

Research paper (scientific journal), Single Work, Accepted

Environmentally Benign and Stereoselective Formation of β-O-Glycosidic Linkages Using Benzyl-Protected Glucopyranosyl Phosphite and Montmorillonite K-10

H. Nagai, S. Matsumura, K. Toshima

Tetrahedron Letters, 43    847-850 2002.01

Joint Work

Lipase-catalyzed selective transformation of polycaprolactone into cyclic dicaprolactone and its repolymerization in supercritical carbon dioxide

Kondo Reiko, Toshima Kazunobu, Matsumura Shuichi

Macromolecular Bioscience (Wiley-VCH)  2 ( 6 ) 267-271 2002

Research paper (conference, symposium, etc.), Joint Work, Accepted

Synthetic Studies on Apoptolidin: Synthesis of the C1-C21 Macrolide Fragment

T. Arita, K. Kato, D. Tanaka, S. Matsumura, K. Toshima

Tetrahedron Letters, 42    8873-8876 2001.12

Joint Work

酵素リパーゼの応用

ポリマーダイジェスト    531-534 2001.11

Single Work

Organic Solvent-free Enzymatic Transformation of Poly(ε-caprolactone) into Repolymerizable Oligomers in Supercritical Carbon Dioxide

S. Matsumura, H. Ebata, R. Kondo, K. Toshima

Macromolecular Rapid Communications (Wiley-VCH)  22 ( 16 ) 1325-1329 2001.11

Research paper (scientific journal), Joint Work, Accepted

酵素触媒による脂肪族ポリエステルの化学合成

Matsumura Shuichi

エコインダストリー (シーエムシ)  6 ( 11 ) 27-37 2001.09

Research paper (scientific journal), Single Work

Lipase-Catalyzed Ring-Opening Polymerization of β-Butyrolactone: End-Group Analysis of Poly(3-hydroxybutanoate) Using Supercritical Fluid Chromatography

Y. Osanai, K. Toshima, S. Matsumura

Macromolecular Bioscience (Wiley-VCH)  1 ( 5 ) 171-177 2001.08

Research paper (scientific journal), Joint Work, Accepted

A Strategy for Increasing Molecular Weight of Polyester by Lipase-Catalyzed Polymerization

H. Ebata, K. Toshima, S. Matsumura

Chemistry Letters (日本化学会)  2001 ( 8 ) 789-799 2001.08

Research paper (scientific journal), Joint Work, Accepted

酵素を触媒とする生分解性脂肪族ポリエステルの合成およびモノマー化リサイクル

Matsumura Shuichi

高分子 (高分子学会)  50 ( 6 ) 392 2001.06

Research paper (scientific journal), Single Work, Accepted

Novel Stereocontrolled α- and β-Glycosidations of Mannopyranosyl Sulfoxides Using Environmentally Benign Heterogeneous Solid Acids

H. Nagai, K. Kawahara, S. Matsumura, K. Toshima

Tetrahedron Letters, 42    4159-4162 2001.06

Joint Work

Involvement of Catalytic Amino Residues in Enzyme-Catalyzed Polymerization for the Synthesis of Polyesters

Y. Suzuki, S. Taguchi, T. Saito, K. Toshima, S. Matsumura, Y. Doi

Biomacromolecule (ACS)  2 ( 2 ) 541-544 2001.04

Research paper (scientific journal), Joint Work, Accepted

The First Total Synthesis of Concanamycin F (Concanolide A)

T. Jyojima, N. Miyamoto, M. Katohno, M. Nakata, S. Matsumura, K. Toshima

The Journal of Organic Chemistry, 66    1708-1715 2001.03

Research paper (scientific journal), Joint Work

酵素を用いる環境低負荷高分子創製とモノマー化リサイクルへの新ルート

MATSUMURA SHUICHI

新技術フォーラム２００１ (財団法人　神奈川高度技術支援財団（ＫＴＦ）)   2001.02

Research paper (other academic), Single Work

Lipase-catalyzed transformation of poly(trimethylene carbonate) into cyclic monomer, trimethylene carbonate: A new strategy for sustainable polymer recycling using an enzyme

S. Matsumura, S. Harai, K. Toshima

Macromolecular Rapid Communications 22 ( 3 ) 215-218 2001.02

Research paper (scientific journal), Joint Work, Accepted

Novel enzyme-catalyzed ring-opening polymerization of glycidol

Y. Soeda, K. Toshima, S. Matsumura

Chemistry Letters (日本化学会)  2001 ( 1 ) 76-77 2001.01

Research paper (scientific journal), Joint Work, Accepted

A novel promoter, heteropoly acid, mediated chemo- and stereoselective sulfoxide glycosidation reactions

H. Nagai, S. Matsumura, K. Toshima

Tetrahedron Letters, 52    10233-10237 2000.12

Research paper (scientific journal), Joint Work

Lipase-catalyzed transformation of poly(ε-caprolactone) into cyclic dicaprolactone

H. Ebata, K. Toshima, S. Matsumura

Biomacromolecules (ACS)  1 ( 4 ) 511-514 2000.12

Research paper (scientific journal), Joint Work, Accepted

Novel stereocontrolled glycosidations using a heterogeneous and environmentally benign solid acid, sulfated zirconia (SO_4_/ZrO_2_)

K. Kasumi, S. Matsumura, K. Toshima

International Chemical Congress of Pacific Basin Societies  2000.12

Joint Work, Accepted

Chemical synthesis and DNA photocleavage of the intercalator-carbohydrate hybrid moiety of the necarzinostatin chromophore

S. Takai, Y. Maeda, R. Takano, S. Matsumura, K. Toshima

Angewandte Chemie, Internatinal Edition, 39    3656-3658 2000.11

Joint Work

New route for sustainable biodegradable polymer synthesis and recycling using an enzyme

KAIST-TIT symposium on biodegradable polymer for eco-system and biomedical application  2000.10

Single Work, Accepted

Carbohydrate-mediated DNA photocleavage: Design, synthesis, and evaluation of novel glycosyl anthraquinones

Y. Maeda, H. Ouchi, A. Asai,S. Matsumura, K. Toshima

Bioorganic & Medicinal Chemistry Letters, 10    2163-2165 2000.10

Joint Work

Lipase-catalyzed polymerization of diethyl carbonate and diol to aliphatic poly(alkylene carbonate)

S. Harai, K. Toshima, S. Matsumura

Macromolecular Chemistry and Physics (Wiley-VCH)  201 ( 14 ) 1632-1639 2000.09

Research paper (scientific journal), Joint Work, Accepted

A new strategy for sustainable polymer recycling using enzyme: poly(ε-caprolactone)

S.Matsumura, H. Ebata, K. Toshima

Macromolecular Rapid Communications (Wiley-VCH)  21 ( 12 ) 860-863 2000.08

Research paper (scientific journal), Joint Work, Accepted

One-step synthesis of n-octyl β-D-xylotrioside, xylobioside and xyloside from xylan and n-octanol using acetone powder of Aureobasidium pullulans in supercritical fluids

T. Nakamura, K. Toshima, S.Matsumura

Biotechnology Letters, 22    1183-1189 2000.07

Joint Work

Lipase-catalyzed reaction of molecularly pure linear and cyclic poly(3-hydroxybutanoate)s: Evidence of cyclic polymer formation

Y. Osanai, K. Toshima, S.　Matsumura

Chemistry Letters (日本化学会)  2000 ( 5 ) 576-577 2000.05

Research paper (scientific journal), Joint Work, Accepted

Enzyme-catalyzed ring-opening polymerization of β-butyrolactone using PHB depolymerase

Suzuki Yoichi, Ohura Takeshi, Kasuya Ken-ichi, Doi Yoshiharu, Toshima Kazunobu, Matsumura Shuichi

Chemistry Letters (日本化学会)  2000 ( 3 ) 318-319 2000.04

Research paper (scientific journal), Joint Work, Accepted

Novel lipase-catalyzed ring-opening copolymerization of oxiranes and dicarboxylic anhydride forming polyesters bearing carboxyl groups and their physicochemical properties and biodegradability

S. Matsumura, T. Okamoto, K. Tsukada, N. Mizutani, K. Toshima

Macromolecular Symposia, 144    219-235 2000.02

Joint Work

2-Phenylquinoline-carbohydrate hybrids: molecular design, chemical synthesis, and evaluation of a new family of light-activatable DNA-cleaving agents

K. Toshima, R. Takano, Y. Maeda, M. Suzuki, A. Asai, S. Matsumura

Angewandte Chemie International Edition, 38(24)    3733-3735 1999.12

Joint Work

Novel poly(vinyl alcohol)-degrading enzyme and the degradation mechanism

S. Matsumura, N. Tomizawa, A. Toki, K. Nishikawa, K. Toshima

Macromolecules (ACS)  32 ( 23 ) 7753-7761 1999.11

Research paper (scientific journal), Joint Work, Accepted

Enzymatic Preparation and Biodegradation of Polyaspartate

S. Matsumura, N. Otozawa, K. Toshima

7th SPSJ International Polymer Conference (IPC 99), (Yokohama)  1999.10

Joint Work

Total synthesis of C-glycosylangucycline, urdamycinone B, using an unprotected sugar

G. Matsuo, Y. Miki, M. Nakata, S. Matsumura, K. Toshima

The Journal of Organic Chemistry, 64(19)    7101-7106 1999.10

Research paper (scientific journal), Joint Work

Novel lipase-catalyzed ring-opening copolymerization of lactide and trimethylene carbonate forming poly(ester carbonate)s

S. Matsumura, K. Tsukada, K. Toshima

International Journal of Biological Macromolecules, 25 (Elsevier)  25 ( 1-3 ) 161-167 1999.10

Research paper (scientific journal), Joint Work, Accepted

Novel dehydrative glycosidations of 1-hydroxy sugars using a heteropoly acid

K. Toshima, H. Nagai, S. Matsumura

Synlett, (9)    1420-1422 1999.09

Joint Work

Enzymatic synthesis of aliphatic polycarbonate from diethyl carbonate and diol

S. Matsumura, S. Harai, K. Toshima

IUPAC International Symposium on Ionic Polymerization (IP'99), (Kyoto)  1999.07

Joint Work, Accepted

Novel stereocontrolled glycosidations of olivoses using montmorillonite K-10 as an environmentally benign catalyst

T. Jyojima, N. Miyamoto, Y. Ogawa, S. Matsumura, K. Toshima

Tetrahedron Letters, 40(27)    5023-5026 1999.07

Joint Work

Biocatalytic one-step synthesis of n-octyl β-D-xylotrioside and xylobioside from xylan and n-octanol in supercritical carbon dioxide

Matsumura Shuichi, Nakamura Takehiro, Yao Eiya, Toshima Kazunobu

Chemistry Letters (日本化学会)  1999 ( 7 ) 581-582 1999.07

Research paper (scientific journal), Joint Work, Accepted

Enzymatic synthesis of poly(tetramethylene carbonate) from diethyl carbonate and 1,4-butanediol

S. Matsumura, S. Harai, K. Toshima

Proceedings of the Japan Academy, 75, Ser. B 75 ( 6 ) 117-121 1999.07

Research paper (conference, symposium, etc.), Joint Work, Accepted

Enzymatic synthesis, surface activity, antimicrobial properties and biodegradability of di, and triglycerol fatty acid esters

S. Matsumura, M. Maki, K. Toshima, K. Kawada

Journal of Japan Oil Chemists’ Society (日本油化学協会)  48 ( 7 ) 681-692 1999.07

Research paper (scientific journal), Joint Work, Accepted

Enzyme-catalyzed ring-opening polymerization of β-butyrolactones

Y. Osanai, K. Toshima, S. Matsumura

IUPAC International Symposium on Ionic Polymerization (IP'99), (Kyoto)  1999.07

Joint Work, Accepted

Novel stereocontrolled glycosidations of 2-deoxyglucopyranosyl fluoride using a heterogeneous solid acid, sulated zirconia (SO_4_/ZrO_2_)

K. Toshima, K. Kasumi, S. Matsumura

Synlett, (6)    813-815 1999.06

Joint Work

One-step preparation of alkyl β-D-glucopyranoside by the transglycosylation of chitosan and alcohol using purified exo-β-D-glucosaminidase

Matsumura Shuichi, Yao Eiya, Toshima Kazunobu

Biotechnology Letters 21 ( 5 ) 451-456 1999.05

Research paper (scientific journal), Joint Work, Accepted

Novel direct preparation of n-butyl 2-amino-2-deoxy-β-D-glucopyranoside from chitosan and n-butanol using biocatalyst

Matsumura Shuichi, Yao Eiya, Sakiyama Kazuya, Toshima Kazunobu

Chemistry Letters (日本化学会)  1999 ( 5 ) 373-374 1999.05

Research paper (scientific journal), Joint Work, Accepted

Engymatic preparation of malate-based polycarboxylates having higher molecular weights by copolymerization with lactone

Matsumura Shuichi, Beppu Hideki, Toshima Kazunobu

Chemistry Letters (日本化学会)  1999 ( 3 ) 249-250 1999.03

Research paper (scientific journal), Joint Work, Accepted

　View Summary

リパーゼを用いマロラクトンベンジルエステルとプロピオラクトンを共重合させることで高分子量を有するポリカルボン酸が得られることを記した。

Preparation of octyl β-D-xylobioside and xyloside by xylanase-catalyzed direct tranglycosylation reaction of xylan and octanol

Matsumura Shuichi, Sakiyama Kazuya, Toshima Kazunobu

Biotechnology Letters 21 ( 2 ) 17-22 1999.02

Research paper (scientific journal), Joint Work, Accepted

　View Summary

キシラン資化菌から単離したキシラナーゼを用い、キシランとオクタノールからのアルキルキシロビオシド及びアルキルキシロシド生成のメカニズムと最適条件について報告した。

One-pot synthesis of 1-octyl β-D-glucoside from cellulose and 1-octanol by the combination of cellulase and β-glucosidase

Matsumura Shuichi, Tsuruta Hirohumi, Toshima Kazunobu

Journal of Japan Oil Chemists Society 48 ( 1 ) 15-19 1999.01

Research paper (scientific journal), Joint Work, Accepted

　View Summary

セルロースとオクタノールよりセルラーゼとβ-グルコシダーゼの組み合わせによるワンポット合成によりオクチル β-D-グルコシドが得られることについて記した。

Enzyme-catalyzed polymerization of L-aspartate

Matsumura Shuichi, Tsushima Yasuhiro, Otozawa Nobuyuki, Murakami Saeko, Toshima Kazunobu

Macromolecular Rapid Communications 20 ( 1 ) 7-11 1999.01

Research paper (scientific journal), Joint Work, Accepted

　View Summary

アルカリプロテアーゼを用いるＬ―アスパラギン酸エステルの重合について報告した。

無保護のＣ―グリコシル化反応の開発と生理活性物質合成への応用

戸嶋一敦、松尾剛、中田雅也、松村秀一

有機合成化学協会誌、56(10)  1998.10

Research paper (scientific journal), Joint Work

　View Summary

無保護糖を用いたアリールおよびアリルC-グリコシル化反応の開発とアリールC-グリコシル化反応による生理活性物質の合成について報告した。

Lipase-catalyzed ring-opening polymerization of β-butyrolactone to the cyclic and linear poly(3-hydroxybutyrate),

Matsumura Shuichi, Suzuki Yoichi, Keisuke Tsukada, Kazunobu Toshima, Doi Yoshiharu, Kasuya Ken-ichi

Macromolecules (ACS)  ３１ ( １９ ) 6444-6449 1998.09

Research paper (scientific journal), Joint Work, Accepted

　View Summary

リパーゼを用いるβーブチロラクトンの開環重合によりポリ（３ーヒドロキシブタン酸）が生成することを報告した。その際、Ｒ体のラクトンの重合性が優れることについて考察を行った。

Novel Glycosidations of Glycals Using BCl_3_ or BBr_3_ as a Promoter for Catalytic and Stereoselective Syntheses of 2-Deoxy-α-glycosides,

戸嶋一敦、永井秀幸、宇敷康信、松村秀一

Synlett, (9)  1998.09

Joint Work

　View Summary

ボロントリクロリドおよびボロントリブロミドを新しい活性化剤に用いたグリカールの高立体選択的グリコシル化反応により、2-デオキシ-α-グリコシドが高収率で得られることを見出した。

Novel Stereocontrolled glycosidations using a solid acid, SO4/ZrO2, for direct synthesis of α- and β-mannopyranosides

戸嶋一敦、霞健一、松村秀一

Synlett (6)  1998.06

Joint Work

　View Summary

固体酸硫酸化ジルコニアを触媒とする高立体選択的グリコシル化反応によるα-およびβ-マンノピラノシドの合成法を開発した。

Synthetic studies on concanamycin A: Synthesis of the C5-C13 and C20-C28 segments,

城島孝明、上遠野正孝、宮本直樹、中田雅也、松村秀一、戸嶋一敦

Tetrahedron Letters, 39  1998.06

Joint Work

　View Summary

１８員環マクロリド抗生物質コンカナマイシンAのC5-C13 および C20-C28セグメントを合成した。

Synthetic studies on concanamycin A: Total synthesis of concanolide A (concanamycin F)

城島孝明、宮本直樹、上遠野正孝、中田雅也、松村秀一、戸嶋一敦

Tetrahedron Letters, 39  1998.06

Joint Work

　View Summary

１８員環マクロリド抗生物質コンカナマイシンAのアグリコンのコンカナノリドA（コンカナマイシンＦ）の最初の全合成を達成した。

Novel lipase-catalyzed ring-opening copolymerization of oxiranes and succinic anhydride forming polyesters bearing functional groups

Matsumura Shuichi, Okamoto Takeshi, Tsukada Keisuke, Toshima Kazunobu

Macromolecular Rapid Communications 19 ( 6 ) 295-298 1998.06

Research paper (scientific journal), Joint Work, Accepted

　View Summary

リパーゼを用いオキシランとジカルボン酸無水物との重合によりカルボキシル基やフェニル基を有するポリエステルの合成を行った。

Novel ring-opening polymerization of lactide by lipase

Matsumura Shuichi, Mabuchi Kimihiro, Toshima Kazunobu

Macromolecular Symposia 130 ( 6 ) 285-304 1998.06

Research paper (scientific journal), Joint Work, Accepted

　View Summary

リパーゼによるラクチドの開環重合について重合条件の検討を行った。

Aryl and allyl C-glycosydation methods using unprotected sugars

戸嶋 一敦、松尾 剛、石塚 徹、宇敷 康信、中田 雅也、松村 秀一

Journal of Organic Chemistry, 63 63 1998.04

Research paper (scientific journal), Joint Work, Accepted

　View Summary

無保護糖を用いたアリールおよびアリルC-グリコシル化反応の開発

Surface Activity, Antimicrobial Properties and Biodegradability of n-Alkyl Xylosides, Xylobiosides, and Xylotriosides

Matsumura Shuichi, Ando Seiichiro, Kazunobu Toshima, Kawada Kazuo

Journal of Japan Oil Chemists Society (日本油化学協会)  47 ( 3 ) 247-255 1998.03

Research paper (scientific journal), Joint Work, Accepted

　View Summary

アルキルキシロシド、キシロビオシドおよびキシロトリオシドの界面活性、抗菌性、および生分解性について系統的検討を行った。

Preparation and Properties of Chitosan-Derived Biodegradable Polymeric Surfactant

Isananto Winursito, Toshima Kazunobu, Matsumura Shuichi

Journal of Japan Oil Chemists Society, 47(3) (日本油化学協会)  47 ( 3 ) 239-246 1998.03

Research paper (scientific journal), Joint Work, Accepted

　View Summary

ジカルボキシル化キトサンのアシル化体について高分子界面活性剤としての評価を行った。

One-pot synthesis of alkyl β-D-xylobioside from xylan and alcohol by acetone powder of Aureobasidium pullulans

Matsumura Shuichi, Sakiyama Kazuya, Toshima Kazunobu

Biotechnology Letters 19 ( 12 ) 1249-1253 1997.12

Research paper (scientific journal), Joint Work, Accepted

　View Summary

糖転移能を有するキシラナーゼ産生菌Aureobasidium pullulans のアセトンパウダーを酵素源にキシランとアルコールからのアルキルキシロビオシドのワンポット合成について記した。

Artificial Anthraquinone-carbohydrate hybrids: Design and synthesis, DNA binding, and cytotoxicity

戸嶋一敦、大内拡美、岡崎自子、狩野孝明、森口誠、浅井章良、松村秀一

Angewandte Chemie,International Edition, 36 36 1997.12

Research paper (scientific journal), Joint Work, Accepted

　View Summary

人工アントラキノン-糖ハイブリッド分子を分子設計および化学合成し、これがDNAの特定塩基配列に結合し、細胞毒性を有することを見出した。

Environmentally Benign Aryl C-Glycosidations of Unprotected Sugars Using Montmorillonite K-10 as a Solid Acid

戸嶋一敦、宇敷康信、松尾剛、松村秀一

Tetrahedron Letters, 38(42) 38 ( 42 )  1997.10

Research paper (scientific journal), Joint Work, Accepted

　View Summary

環境適応型固体酸モンモリロナイトK-10を触媒とする無保護糖のアリールＣ-グリコシル化反応を開発した。

酵素を用いる生分解性ポリマー合成法の新展開

松村秀一（総説）

機能材料、17(9)  1997.09

Research paper (scientific journal), Joint Work

　View Summary

酵素を用いるポリマーの合成についてまとめた。

R-Enantioselective galactosylation of secondary alcohols using β-galactosidase

Matsumura Shuichi, Yamazaki Hiroki, Toshima Kazunobu

Biotechnology Letters 19 ( 6 ) 583-586 1997.06

Research paper (scientific journal), Joint Work, Accepted

　View Summary

βーガラクトシダーゼによる２級アルコールのＲ―エナンチオ選択的ガラクトシル化について報告を行った。

Novel C-3 Epimerization of Digitoxosides to Olivosides Under Hydrogenolysis Conditions

戸嶋一敦、稲垣京子、中田雅也、松村秀一

Synlett, 1997(6)  1997.06

Research paper (scientific journal), Joint Work, Accepted

　View Summary

糖のジギトキソシドが、加水素分解条件下において、C-3位のエピマー化を伴って、オリボシドに変換されることを見出した。

Enzyme-Catalyzed Ring-Opening Polymerization of 1,3-Dioxane-2-one to Poly(trimethylene carbonate)

Matsumura Shuichi, Tsukada Keisuke, Toshima Kazunobu

Macromolecules 30 ( 10 ) 3122-3124 1997.05

Research paper (scientific journal), Joint Work, Accepted

　View Summary

1,3-ジオキサン-2-オンの酵素触媒開環重合によるポリ（トリメチレンカーボネート）の合成について記した。

Novel Heterocyclic Enediynes. Molecular Design, Chemical Synthesis and DNA Cleavage

戸嶋一敦、大石清、富島美帆、松村秀一

Heterocycles, 45(5)  1997.05

Joint Work

　View Summary

新規ヘテロエンジイン化合物の分子設計、化学合成とDNA切断活性評価を行った。（5頁）

Total Synthesis of Bafilomycin A1

戸嶋一敦、城島孝明、山口弘之、野口泰信、吉田武人、村瀬秀明、中田雅也、松村秀一

The Journal of Organic Chemistry, 62(10)  1997.05

Research paper (scientific journal), Joint Work

　View Summary

液胞型Ｈ＋―ATPaseを特異的に阻害する抗生物質バフィロマイシンA1の 最初の全合成を達成した。（14頁）

Molecular Design of Biodegradable Functional Polymers, 5. Enzymatic Degradation of Polycarboxylates Containing Vinyl Alcohol Blocks as Biodegardable Segment

Matsumura Shuichi, Shimagami Youko, Kanamaru Minako, Toshima Kazunobu

Macromolecular Chemistry and Physics 198 ( 5 ) 2291-2305 1997.05

Research paper (scientific journal), Joint Work, Accepted

　View Summary

ビニルアルコールブロックを生分解性部分に有するポリカルボン酸塩の酵素分解について検討を行った。

Lipase-Catalyzed Ring-Opening Polymerization of Lactide

Matsumura Shuichi, Mabuchi Kimihiro, Toshima Kazunobu

Macromolecular Rapid Communications 18 ( 4 ) 477-482 1997.04

Research paper (scientific journal), Joint Work, Accepted

　View Summary

リパーゼによるラクチドの開環重合について報告を行った。

Preparation of Novel Biodegradable Polyampholyte: Partially Dicarboxylated Chitosan

Matsumura Shuichi, Yokochi Eiji, Winursito Isananto, Toshima Kazunobu

Chemistry Letters (日本化学会)  1997 ( 3 ) 215-216 1997.03

Research paper (scientific journal), Joint Work, Accepted

　View Summary

新規な生分解性両性物質として部分ジカルボキシル化キトサンの合成について報告した。

Enzymatic Synthesis of Alkyl Xylobioside and Xyloside from Xylan and Alcohol

Matsumura Shuichi, Kinta Yasuyoshi, Sakiyama Kazuya, Toshima Kazunobu

Biotechnology Letters 18 ( 11 ) 1335-1340 1996.11

Research paper (scientific journal), Joint Work, Accepted

　View Summary

キシランとアルコールからのアルキルキシロビオシドとキシロシドの酵素合成について記した。

Environmentally Compatible C-Glycosidation of Glycals using Montmorillonite K-10

戸嶋一敦、宮本直樹、松尾剛、中田雅也、松村秀一

Chemical Communications (11)  1996.11

Joint Work

　View Summary

環境適応型固体酸モンモリロナイトK-10を触媒とするグリカールのC-グリコシル化反応を開発した。

Novel Designed Enediynes: Molecular Design, Chemical Synthesis, Mode of Cycloaromatization, and Guanine-specific DNA Cleavage

戸嶋一敦、太田和実、狩野孝明、中村岳嗣、中田雅也、木下光博、松村秀一

Bioorganic and Medicinal Chemistry, 4  1996.10

Joint Work

　View Summary

DNAのグアニン塩基を選択的に切断する人工エンジイン化合物の分子設計、化学合成と機能評価を行った。（9頁）

Enzyme-Catalyzed Ring-Opening Polymerization of β-Propiolactone

Matsumura Shuichi, Beppu Hideki, Tsukada Keisuke, Toshima Kazunobu

Biotechnology Letters 18 ( 9 ) 1041-1046 1996.09

Research paper (scientific journal), Joint Work, Accepted

　View Summary

βープロピオラクトンの開環重合について酵素起源や重合条件について検討を行った。

Preparation of Poly(β-malic acid) by Enzymatic Ring-Opening Polymerization of Benzyl β-Malolactonate

Matsumura Shuichi, Beppu Hideki, Nakamura Kazuhiro, Shuichi Osanai, Toshima Kazunobu

Chemistry Letters (日本化学会)  1996 ( 9 ) 795-796 1996.09

Research paper (scientific journal), Joint Work, Accepted

　View Summary

リパーゼ触媒によるβーベンジルマロラクトネートの開環重合によるポリ（βーリンゴ酸）の合成について報告を行った。

Two-step Synthesis of C-Glycosyl Juglones from Unprotected Sugars: A Novel Approach to Angucycline Antibitotics

松尾剛、松村秀一、戸嶋一敦

Chemical Communications (18)  1996.09

Joint Work

　View Summary

アングサイクリン系抗生物質の合成中間体として重要なC-グリコシルジュグロンを無保護糖から２段階で合成する方法を開発した。

ポリマーの生分解とリサイクル

松村秀一（総説）

化学と教育、44(9)  1996.09

Research paper (scientific journal), Joint Work

　View Summary

生分解性ポリマーの生分解機構とリサイクルについてまとめた。

生分解性を有する機能化多糖の設計

松村秀一

高分子、45(8)  1996.08

Research paper (scientific journal), Joint Work

　View Summary

部分ジカルボキシル化多糖の生分解性と機能について述べた。

Biodegradability, Hydrolytic Degradability and Builder Performance of Starch-Based Polycarboxylates Derived from Tropical Plants

I. Winursito, Matsumura Shuichi

Journal of Japan Oil Chemists Society (日本油化学協会)  45 ( 8 ) 723-730 1996.08

Research paper (scientific journal), Joint Work, Accepted

　View Summary

タピオカ、サゴおよびコーンスターチの部分ジカルボキシル体について、生分解性と合成洗剤用ビルダー機能について系統的検討を行った。

エンジイン系人工DNA切断分子の設計と合成

戸嶋一敦、中田雅也、松村秀一

有機合成化学協会誌、54  1996.06

Research paper (scientific journal), Joint Work

　View Summary

エンジイン系人工DNA切断分子の分子設計、化学合成と機能評価の検討を行った。（13頁）

水溶性ポリマーの生分解性と機能

Matsumura Shuichi

繊維と工業 (繊維学会)  52 ( 5 ) P-209-215 1996.05

Research paper (scientific journal), Single Work

Biodegradability, Hydrolytic Degradability, and Builder Performance in Detergent Formulations of Partially Dicarboxylated Alginic Acid

Isananto Winursito, Matsumura Shuichi

Journal of Environmental Polymer Degradation (Plenum Publishing)  4 ( 2 ) 113-121 1996.04

Research paper (scientific journal), Joint Work, Accepted

　View Summary

部分ジカルボキシル化アルギン酸の生分解性、加水分解性及び合成洗剤中でのビルダー機能について記した。

Enzymatic Synthesis of Polycarboxylates Containing Ester Linkages in the Backbone

Matsumura Shuichi, Beppu Hideki, Toshima Kazunobu

PMSE (American Chemical Society, Division of Polymeric Materials:Science & Engineering), 74 74 ( 1 ) 2 1996.03

Research paper (scientific journal), Joint Work

　View Summary

リパーゼ触媒によるβーベンジルマロラクトネートの開環重合により得られる主鎖中にエステル結合を有するポリカルボン酸塩のについて生分解性素材としての検討を行った。

Total Synthesis of Bafilomycin A1. 2. The Assemblage and Completion of the Synthesis

戸嶋一敦、山口弘之、城島孝明、野口泰信、中田雅也、松村秀一

Tetrahedron Letters, 37  1996.02

Joint Work

　View Summary

液胞型Ｈ＋―ATPaseを特異的に阻害する抗生物質バフィロマイシンA1の 最初の全合成を達成した。（4頁）

Total Synthesis of Urdamycinone B via C-Glycosidation of Unprotected Sugar and Diels-Alder Reaction of C-Glycosyl Juglone

松尾剛、三樹祐子、中田雅也、松村秀一、戸嶋一敦

Chemical Communications (4)  1996.02

Joint Work

　View Summary

無保護糖のC-グリコシル化反応とディールズ-アルダー反応を鍵反応とし、抗腫瘍性抗生物質ウルダマイシノンBの全合成を達成した。（2頁）

Total Synthesis of Bafilomycin A1. 1. Syntheses of the C5〜C11, C12〜C17 and C18〜C25 Segments

戸嶋一敦、城島孝明、山口弘之、村瀬秀明、吉田武人、松村秀一、中田雅也

Tetrahedron Letters, 37  1996.02

Joint Work

　View Summary

液胞型Ｈ＋―ATPaseを特異的に阻害する抗生物質バフィロマイシンA1の C5〜C11, C12〜C17およびC18〜C25 位に相当するセグメントを合成した。（4頁）

オイルコーナー　セクション１２　Detergents/Cosmetics

MATSUMURA SHUICHI

油化学 (日本油化学協会)   ( 1 ) 289 1996.01

Research paper (scientific journal), Single Work

Molecular Design of Biodegradable Functional Polymer, 4: Poly(vinyl alcohol) Block as Biodegradable Segment

Matsumura Shuichi, Shimura Yukimasa, Toshima Kazunobu, Tsuji Masao, Hatanaka Tadashi

Macromolecular Chemistry and Physics 196 ( 11 ) 3437-3445 1995.11

Research paper (scientific journal), Joint Work, Accepted

　View Summary

生分解性を有する機能性ポリマーの分子設計としてポリビニルアルコールブロックを生分解性セグメントに有するものについて検討を行った。

Design of Biodegradable High Molecular Weight Polycarboxylates and Their Application in a Detergent Field

松村秀一

Oils-Fats-Lipids, , PJ Barnes & Associates (1995).    427-431 1995.10

Single Work

　View Summary

生分解性を有する水溶性ポリマーの分子設計と、これらを合成洗剤用ビルダーとして用いた時の性能について、分子構造との相関関係を報告した。（総説）

Novel Dienediyne Systems Related to the Neocarzinostatin Chromophore: Molecular Design, Chemical Synthesis, and Evaluation

戸嶋一敦、太田和実、柳川幸二、狩野孝明、中田雅也、木下光博、松村秀一

Journal of the American Chemical Society, 117  1995.10

Research paper (scientific journal), Joint Work

　View Summary

抗腫瘍性抗生物質ネオカルチノスタチンをモチーフとした人工ジエンジイン化合物の分子設計、化学合成およびDNA切断に関する機能評価を行った。（7頁）

Molecular Design, Chemical Synthesis, and Study of Novel Enediyne-Sulfide Systems Related to the Neocarzinostatin Chromophore

戸嶋一敦、太田和実、大橋文、中村岳嗣、中田雅也、竜田邦明、松村秀一

Journal of the American Chemical Society, 117  1995.05

Research paper (scientific journal), Joint Work

　View Summary

抗腫瘍性抗生物質ネオカルチノスタチンをモチーフとした人工エンジイン化合物の分子設計、化学合成およびDNA切断に関する機能評価を行った。（10頁）

生分解性を有する水溶性ポリマーの設計と機能

松村 秀一

PETEROTECH 18 ( 3 ) 207-211 1995.03

Research paper (scientific journal), Single Work

生分解性を有する水溶性ポリマーの設計と油化学領域への応用に関する研究

Matsumura Shuichi

油化学 (日本油化学協会)  44 ( 2 ) 97-107 1995.02

Research paper (scientific journal), Single Work

　View Summary

生分解性を有する水溶性ポリマーの分子設計について著者らのこれまでの研究をまとめ、さらにこれらを合成洗剤用ビルダーとして用いた時の性能評価を行い、分子構造との相関関係を報告した。（総説）

生分解性を有する水溶性ポリマーの最近の研究

松村秀一（総説）

杉山産業研究所研究報告、1994  1994.12

Research paper (other academic), Single Work

Effects of Molecular Weight and Stereoregularity on Biodegradation of Poly(vinyl alcohol) by Alcaligenes faecalis

Matsumura Shuichi, Shimura Yukimasa, Terayama Koutaro, Kiyohara Takato

Biotechnology Letters, 16(11) 16 ( 11 ) 1205-1210 1994.11

Research paper (scientific journal), Joint Work, Accepted

　View Summary

ポリビニルアルコールの分子量及び立体規則性の生分解性に及ぼす影響についてPVA 資化菌Alcaligenes faecalis を用いて検討を行った。

Biodegradability and Builder Performance in Detergents of Poly(sodium carboxylate) Containing Glycopyranose Residues in the Backbone

Matsumura Shuichi, Yoshikawa Sadao

Polymer Degradation and Stabilization 45 ( 10 ) 233-239 1994.10

Research paper (scientific journal), Joint Work, Accepted

　View Summary

主鎖中に糖を含有するポリカルボン酸塩の生分解性と合成洗剤用ビルダー機能について記した。

Design, Cycloaromatization and Guanine-selective DNA Cleavage of Novel Enediynes

戸嶋一敦、太田和実、狩野孝明、中村岳嗣、中田雅也、松村秀一

Journal of the Chemical Society, Chemical Communications, 1994  1994.10

Research paper (scientific journal), Joint Work

　View Summary

DNAのグアニン塩基を選択的に切断する人工エンジイン化合物の合成と機能評価を行った。（2頁）

Biodegradation of poly(vinyl alcohol) and vinyl alcohol block as biodegradable segment

松村秀一、志村幸祐、戸嶋一敦

Polymer Preprints (American Chemical Society), 35(2) 35 ( 2 ) 429-430 1994.08

Research paper (conference, symposium, etc.), Joint Work

　View Summary

生分解性を有する機能性ポリマーの分子設計のために、ポリビニルアルコールおよび生分解性セグメントとしてのビニルアルコールブロックの生分解性について検討を行った。

Buider Performance in Detergent Formulations and Biodegradability of Partially Dicarboxylated Amylopectin

Matsumura Shuichi, Aoki KIyotaka, Toshima Kazunobu

Journal of the American Oil Chemical Society (The American Oil Chemical Society)  71 ( 7 ) 749-755 1994.07

Research paper (scientific journal), Joint Work, Accepted

　View Summary

部分ジカルボキシル化アミロペクチンの生分解性と合成洗剤のビルダー作用について検討を行った。

Microbial Production of (2R,4R)-2,4-Pentanediol by Enantioselective Reduction of Acetylacetone and Stereoinversion of 2,4-Pentanediol

Matsumura Shuichi, Kawai Yoko, Takahashi Yoshinori, Toshima Kazunobu

Biotechnology Letters 16 ( 5 ) 485-490 1994.05

Research paper (scientific journal), Joint Work, Accepted

　View Summary

アセチルアセトンのエナンチオ選択的還元及び 2,4-ペンタンジオールの立体反転による(2R,4R)-2,4-ペンタンジオールの微生物を用いる生産

Novel Malonate-Type Copolymers Containing Vinyl Alcohol Blocks as Biodegradable Segments and Their Builder Performance in Detergent Formulations

Matsumura Shuichi, Tanaka Toshiyuki

Journal of Environmental Polymer Degradation (Plenum Publishing Corporation)  2 ( 2 ) 89-97 1994.04

Research paper (scientific journal), Joint Work, Accepted

　View Summary

ビニルアルコールを生分解性セグメントに有する新規マロン酸型コポリマーの合成洗剤用ビルダー性能について記した。

Synthesis and Antimicrobial Properties of Amphiphilic Sugar Derivatives Containing Sulfur and Nitrogen

Kawada Kazuo, Uchibori Tsuyoshi, Asakura Kouichi, Matsumura Shuichi

Journal of Antibacterial and Antifungal Agents 22 ( 4 ) 213-216 1994.04

Research paper (scientific journal), Joint Work, Accepted

　View Summary

イオウおよび窒素を含有する両親媒性糖誘導体の合成と抗菌性について記した。

Surface Activities, Biodegradability and Antimicrobial Properties of N-Alkyl Glycosylamines

Kawada Kazuo, Yago Kazuo, Zen Shonosuke, Uchibori Tsuyoshi, Matsumura Shuichi

Journal of Antibacterial and Antifungal Agents (The society for Antibacterial and Antifungal Agents)  ２２ ( ２ ) 69-75 1994.01

Research paper (scientific journal), Joint Work, Accepted

　View Summary

N-アルキルグルコサミン誘導体の生分解性および抗菌性について記した。

Antimicrobial Properties of ortho-ortho Direct-Linked Phenolic Oligomers

Matsumura Shuichi, Shiotani Takatoshi, Asakura Kouichi, Kawada Kazuo, Uchibori Tsuyoshi

Journal of Antibacterial and Antifungal Agents (The Society for Antibacterial and Antifungal Agents)  22 ( 1 ) 35-38 1994.01

Research paper (scientific journal), Joint Work, Accepted

　View Summary

オルトーオルト直接結合フェノールオリゴマーの抗菌性について記した。

Design and biodegradable high molecular weight polycarboxylates directed towards detergent builders

松村秀一

Proceedings of IUMRS-ICAM-93, 451-454, Elsevier (1993)  1993.12

Research paper (conference, symposium, etc.), Single Work

　View Summary

洗剤用ビルダーを指向した生分解性を有する高分子量ポリカルボン酸塩の設計について記した。

Molecular Design of Biodegradable Functional Polymers, 3. Biodegradability and functionality of poly[(sodium acrylate)-co-(vinyl alcohol)]

Matsumura Shuichi, Ii Sawako, Higeno Haruo, Tanaka Toshiyuki, Okuda Fumiko, Shimura Yukimasa, Toshima Kazunobu

Macromolecular Chemistry and Physics 194 ( 12 ) 3237-3246 1993.12

Research paper (scientific journal), Joint Work, Accepted

　View Summary

ポリ[(アクリル酸ナトリウム)-co-(ビニルアルコール)]の生分解性と機能について報告を行った。

Biodegradability and Builder Performance in Detergents of Poly(sodium carboxylate) Containing Glycopyranose Residues in the Backbone,

松村秀一、吉川貞雄

Polymer Degradation and Stabilization, 45  1993.11

Joint Work

　View Summary

主鎖中に糖部分を有するポリカルボン酸ナトリウムの生分解性と洗剤用ビルダー性能について記した。

Biodegradability and builder performance of reduced molecular weight polycarboxylates obtained from dicarboxylated polysaccharides

Dannnoue Yukihiro, Matsumura Shuichi

Journal of Japan Oil Chemists' Society (日本油化学協会)  42 ( 11 ) 899-904 1993.11

Research paper (scientific journal), Joint Work, Accepted

　View Summary

ジカルボキシル化多糖を低分子量化することにより得られたポリカルボン酸塩の生分解性とビルダー性能

Cycloaromatization and DNA Cleavage of Novel Enyne-allene Systems

戸嶋一敦、太田和実、大塚敦、松村秀一、中田雅也

Jounal of the Chemical Society,Chemical communications(18)  1993.10

Research paper (scientific journal), Joint Work, Accepted

　View Summary

新規エンインアレン化合物を合成し、芳香環化様式を検討後、DNAを切断することを明らかにした。（3頁）

Design, Synthesis and DNA Cleaving Profiles of Hybrids Containing the Novel Enediyne and Naturally Occurring DNA Intercalator

戸嶋一敦、太田和実、大橋文、中村岳嗣、中田雅也、松村秀一

Jounal of the Chemical Society,Chemical communications(19)  1993.10

Joint Work

　View Summary

人工エンジインと天然物由来のDNAインターカレーターとのハイブリッド化合物を合成し、これらがDNAを塩基選択的に切断することを見出した。（3頁）

生分解性を有する高分子量ポリカルボン酸塩の設計　ー生分解性部分としてのポリビニルアルコールブロックー

Matsumura Shuichi, Tanaka Toshiyuki

高分子論文集、50(10) (高分子学会)  50 ( 10 ) 761-766 1993.10

Research paper (conference, symposium, etc.), Joint Work, Accepted

　View Summary

生分解性を有する高分子量ポリカルボン酸塩の設計として生分解性部分としてのポリビニルアルコールブロックの検討を行った。

Polymeric antioxidants, IV. Phenolic oligomers having direct linkage at ortho positions

Asakura Kouichi, Shiotani Takatoshi, Honda Eitoshi, Matsumura Shuichi

Journal of the Japan Oil Chemists Society (日本油化学協会)  42 ( 9 ) 656-660 1993.09

Research paper (scientific journal), Joint Work, Accepted

　View Summary

オルト位に直接結合を有するフェノールオリゴマーの抗酸化能について記した。

Anaerobic biodegradability of polyvinyl alcohol

Matsumura Shuichi, Kurita Harue, Shimokobe Hisaki

Biotechnology Letters 15 ( 7 ) 749-754 1993.07

Research paper (scientific journal), Joint Work, Accepted

　View Summary

ポリマーの嫌気条件での生分解性について、硫酸還元細菌系で試験・評価を行った。

Builder performance in detergent formulations and biodegradability of poly(sodium carboxylate) containing vinyl alcohol groups

Matsumura Shuichi, Shigeno Haruo, Yoshikawa Sadao

Journal of the American Oil Chemists' Society (The American Oil Chemists' Society)  70 ( 7 ) 659-665 1993.07

Research paper (scientific journal), Joint Work, Accepted

　View Summary

主鎖中にビニルアルコール部分を有するポリカルボン酸塩のビルダー機能及び生分解性について記した。

光学活性ブタンジオールおよびその誘導体の生産と利用

Matsumura Shuichi, Toshima Kazunobu

BIO INDUSTRY (シーエムシー出版)  10 ( 5 ) 265-274 1993.05

Research paper (scientific journal), Joint Work

合成洗剤用ビルダーを指向した生分解性を有する高分子量ポリカルボン酸塩設計

Matsumura Shuichi

油化学 (日本油化学協会)  42 ( 5 ) 333-345 1993.05

Research paper (scientific journal), Single Work, Accepted

　View Summary

合成洗剤用ビルダーを指向した生分解性を有する高分子量ポリカルボン酸塩設計についてまとめた。

Enantioselective production of (S)-3-hydroxybutyric acid, (S)-1,3-butanediol and (R)-1,3-butanediol using methanol yeast

Matsumura Shuichi, Imafuku Hiroshi, Takahashi Yoshinori, Toshima Kazunobu

Chemistry Letters 1993 ( 2 ) 251-254 1993.02

Research paper (scientific journal), Joint Work, Accepted

　View Summary

メタノール酵母を用いる(S)-3-ヒドロキシブチン酸、(S)-1,3-ブタンジオール及び(R)-1,3-ブタンジオールのエナンチオ選択的生産

Builder performance in detergent formulations and biodegradability of partially dicarboxylated cellulose and amylose containing sugar residues in the backbone

Matsumura Shuichi, Nishioka Makoto, Shigeno Haruo, Tanaka Toshiyuki, Yoshikawa Sadao

Die Angewandte Makromolakulare Chemie 205 ( 3539 ) 117-129 1993.02

Research paper (scientific journal), Joint Work, Accepted

　View Summary

主鎖中に糖残基を有する部分ジカルボキシル化セルロース及びアミロースのビルダー機能及び生分解性について記した。

Biodegradable Water-soluble Polycarboxylic Acid Design: Biodegradability and Builder Performance of Polyuronide Containing Sugar Residues in the Backbone

Matsumura Shuichi, Amaya Kiminori, Yoshikawa Sadao

Journal of Environmental Polymer Degradation (Plenum Publishing Corporation)  1 ( 1 ) 23-29 1993.02

Research paper (scientific journal), Joint Work, Accepted

　View Summary

生分解性の水溶性ポリカルボン酸塩の設計として糖を含有するポリウロン酸のビルダー機能と生分解性について検討を行った。

Bacteriostatic activities of water-soluble poly(sodium carboxylate) as a biodegradation factor

Matsumura Shuichi, Shigeno Haruo, Tanaka Nobutoshi, Kawada Kazuo, Uchibori Tsuyoshi

Journal of Antibacterial and Antifungal Agents (The Society for Antibacterial and Antifungal Agents, Japan)  21 ( 1 ) 35-38 1993.01

Research paper (scientific journal), Joint Work, Accepted

　View Summary

水溶性ポリカルボン酸塩の静菌作用と生分解性について記した。

Enzymatic synthesis of novel vinyl monomers bearing β-D-galactopyranosides residure

Matsumura Shuichi, Kubokawa Hiroo, Yoshikawa Sadao

Makromoleculare Chemie, Rapid Communications 14 ( 1 ) 55-58 1993.01

Research paper (scientific journal), Joint Work, Accepted

　View Summary

酵素法による β-ガラクトピラノシド残基を有する新規モノマー合成法について記した。

Surface activities, biodegradability and antimicrobial properties of glucosamine derivatives containing alkyl chains

Matsumura Shuichi, Kawamura Yasushi, Yoshikawa Sadao, Kawada Kazuo, Uchibori Tsuyoshi

Journal of the American Oil Chemists' Society (The American Oil Chemists' Society)  70 ( 1 ) 17-22 1993.01

Research paper (scientific journal), Joint Work, Accepted

　View Summary

アルキル鎖を有するグルコサミン誘導体の界面活性、生分解性および抗菌性について記した。

糖質系界面活性剤の構造と機能

Matsumura Shuichi

表面 30 ( 12 ) 991-1004 1992.12

Research paper (scientific journal), Single Work

　View Summary

糖質系界面活性剤の構造と機能についてまとめた。

生分解性を有する機能性高分子の設計

Matsumura Shuichi

天野工業技術研究所年次報告 (天野工業技術研究所)     10-21 1992.12

Research paper (other academic), Single Work

　View Summary

生分解性を有する機能性高分子の設計についてまとめた。

生分解性を有する多糖系ポリカルボン酸塩の設計と合成洗剤用ビルダー性能

Matsumura Shuichi

有機合成化学協会誌 50 ( 4 ) 292-302 1992.04

Research paper (scientific journal), Single Work, Accepted

　View Summary

生分解性を有する多糖系ポリカルボン酸塩の設計と合成洗剤用ビルダー性能について総合的に記した。

生分解性を有する多糖系ポリカルボン酸塩の設計

Matsumura Shuichi

繊維学会誌（繊維と工業） 48 ( 4 ) P-165 - P-170 1992.04

Research paper (scientific journal), Single Work, Accepted

　View Summary

生分解性を有する多糖系ポリカルボン酸塩の設計についてまとめた。

Affinity of cyclodextrins to hydroperoxides

朝倉　浩一、田中　信敏、叶内　敬之、松村　秀一、吉川　貞雄

Journal of Japan Oil Chemists' Society (日本油化学協会)  41 ( 3 ) 203-206 1992.03

Research paper (scientific journal), Joint Work, Accepted

　View Summary

シクロデキストリンの過酸化物との調和性について報告を行った。

Anaerobic biodegradability of water-soluble high molecular weight polycarboxylate by river sediments

MATSUMURA SHUICHI, Shimokobe Hisaki

Chemistry Letters (日本化学会)  1992   1859-1862 1992

Research paper (scientific journal), Joint Work, Accepted

Surface activities, foam suppression, biodegradability and antimicrobial properties of s-alkyl glucopyranosides

Matsumura Shuichi, Imai Kazuyasu, Yoshikawa Sadao, Kawada Kazuo, Uchibori Tsuyoshi

Journal of Japan Oil Chemists' Society (日本油化学協会)  40 ( 9 ) 709-714 1991.09

Research paper (scientific journal), Joint Work, Accepted

　View Summary

s-アルキルグルコシドの界面化学的性質と生分解性や抗菌性について記した。

Enzymatic synthesis of ω-hydroxyl and n-alkyl β-D-galactopyranosides by the transglycosylation reaction ofβ-galactosidase

Matsumura Shuichi, Kubokawa Hiroo, Yoshikawa Sadao

Chemistry Letters 1991 ( 6 ) 945-948 1991.06

Research paper (scientific journal), Joint Work, Accepted

　View Summary

酵素法による ω-ヒドロキシアルキル及び n-アルキルβ-ガラクトピラノシドの一段階合成法について記した。

有機ビルダー（第２５報）主鎖中にグルコピラノース残基を有するデンプン系ポリカルボン酸塩の生分解性とビルダー作用

Matsumura Shuichi, Kobayashi Rika, Yoshikawa Sadao

油化学 (日本油化学協会)  40 ( 5 ) 415-421 1991.05

Research paper (scientific journal), Joint Work, Accepted

　View Summary

主鎖中にグルコピラノース残基を有するデンプン系ポリカルボン酸塩の生分解性とビルダー作用について記した。

Microbial transformation of sec-hydroxyl group of polyols into carbonyl derivatives by specific oxidation using methanol yeast

松村秀一、河盛とも子、吉川貞雄

Chemistry Letters, 1991  1991.04

Joint Work

　View Summary

メタノール酵母によるポリオール類の２級ヒドロキシル基に対する位置選択的カルボニル化につて記した。

アミロースの部分酸化により得られる主鎖中にグルコピラノースを有するポリカルボン酸の生分解

Matsumura Shuichi, Nishioka Makoto, Yoshikawa Sadao

高分子論文集 (高分子学会)  48 ( 4 ) 231-237 1991.04

Research paper (conference, symposium, etc.), Joint Work, Accepted

　View Summary

生分解性を有する機能性高分子の設計としてアミロースの部分酸化により得られる主鎖中にグルコピラノースを有するポリカルボン酸について検討を行った。

Biological activities of phenolic oligomers (III). Antimicrobial activity of polyvinylphenols containing sulfide linkages

Kawada Kazuo, Uchibori Tsuyoshi, Matsumura Shuichi, Yoshikawa Sadao

Journal of Antibacterial and Antifungal Agents (The Society for Antibacterial and Antifungal Agents)  19 ( 4 ) 167-171 1991.04

Research paper (scientific journal), Joint Work, Accepted

　View Summary

分子内にスルフィド結合を有するポリビニルフェノールオリゴマーの抗菌性について記した。

Novel C-3 epimerization of glycals by metal chlorides

稲葉清、松村秀一、吉川貞雄

Chemistry Letters, 1991  1991.03

Joint Work

　View Summary

金属塩によるグリカール類の新規 C-3 エピメリ化反応について報告した。

Enzymatically degradable poly(carboxylic acid) derived from polysaccharide

Matsumura Shuichi, Nishioka Makoto, Yoshikawa Sadao

Makromoleculare Chemie, Rapid Communications 12 ( 2 ) 89-94 1991.02

Research paper (scientific journal), Joint Work, Accepted

　View Summary

ポリカルボン酸ポリマー主鎖中に糖鎖部分を有する一連の高分子電解質の糖加水分解酵素による主鎖の切断反応について記した。

Surface activities, biodegradability and antimicrobial properties of n-alkyl glucosides, mannosides and galactosides

Matsumura Shuichi, Imai Kazuyasu, Yoshikawa Sadao, Kawada Kazuo, Uchibori Tsuyoshi

Journal of the American Oil Chemists' Society, 67(12) 67 ( 12 ) 996-1001 1990.12

Research paper (scientific journal), Joint Work, Accepted

　View Summary

長鎖アルキル基をアグリコンとして有するグルコシド、マンノシド及びガラクトシドの界面化学的性質と生分解性や抗菌性について記した。

Molecular design of biodegradable functional polymers, 2. Poly(carboxylic acid) containing xylopyranosediyl groups in the backbone

Matsumura Shuichi, Maeda Shuichi, Yoshikawa Sadao

Makromolakulare Chemie 191 ( 10 ) 1269-1275 1990.10

Research paper (scientific journal), Joint Work, Accepted

　View Summary

主鎖中にキシロピラノース残基を有するポリカルボン酸塩の生分解性について記した。

Biological activities of phenolic oligomers (II). Antimicrobial activity of fractionated phenol oligomers and alkylidene-bridged phenol oligomers

Kawada Kazuo, Uchibori Tsuyoshi, Watanabe Shoichiro, Asakura Kouichi, Matsumura Shuichi, Yoshikawa Sadao

Journal of Antibacterial and Antifungal Agents 18 ( 8 ) 375-378 1990.08

Research paper (scientific journal), Joint Work, Accepted

　View Summary

アルキリデン架橋フェノールオリゴマーの抗菌性について記した。

Biological activities of phenolic oligomers (I). Relationship between the degree of addition-condensation of phenolic oligomers and their antimicrobial activity

Uchibori Tsuyoshi, Kawada Kazuo, Watanabe Shoichiro, Asakura Kouichi, Matsumura Shuichi, Yoshikawa Sadao

Journal of Antibacterial and Antifungal Agents (防菌防黴学会)  18 ( 5 ) 215-218 1990.05

Research paper (scientific journal), Joint Work, Accepted

　View Summary

メチレン架橋ポリフェノール類の抗酸化性について記した。

生分解性を有する水溶性高分子

Matsumura Shuichi

材料技術、8(5) (材料技術研究協会)  8 ( 5 ) 164-169 1990.05

Research paper (scientific journal), Joint Work

　View Summary

水溶性のポリマーの生分解性について記した。

Microbial transformation of 2-butyn-1,4-diol into 4-hydroxy-2-butynoic acid by specific oxidation of the hydroxymethyl group

松村秀一、依田伸夫、吉川貞雄

Chemistry Letters, 1990  1990.04

Joint Work

　View Summary

化学合成法では困難な 2-ブチン -1,4- ジオールの片側酸化体の合成を微生物法により行った。

Organic Builders. XXIV. Biodegradation of poly[(sodium acrylate)-co-(2-cyclohexene-1-one)]

Matsumura Shuichi, Maeda Shuichi, Yoshikawa Sadao

Journal of Japan Oil Chemists' Society (日本油化学協会)  39 ( 4 ) 245-249 1990.04

Research paper (scientific journal), Joint Work, Accepted

　View Summary

2-シクロヘキセン-1-オンとアクリル酸ナトリウムの共重合体の生分解性について検討を行った。

Molecular design of biodegradable poly(carboxylic acid)

松村秀一、吉川貞雄

Proceedings of the ACS Division of Polymeric Materials: Science and Engineering, 1990  1990.03

Research paper (conference, symposium, etc.), Joint Work

　View Summary

生分解性を有するポリカルボン酸塩の分子設計について記した。

Antioxidant and antimicrobial effect of phenolic sulfides

Asakura Kouichi, Matsumura Shuichi, Yoshikawa Sadao, Kawada Kazuo, Uchibori Tsuyoshi, Watanabe Shoichiro

Proceedings of ISF-JOCS World Congress 1988    556-562 1989.10

Research paper (conference, symposium, etc.), Joint Work

　View Summary

生分解性を有する高分子電解質のビルダー機能について記述した。

洗剤用ビルダーに関する研究　２：酸化デンプン及びアミロースの生分解性とビルダー作用

Matsumura Shuichi, Nishioka Makoto, Yoshikawa Sadao

化学素材研究振興財団研究報告 (化学素材研究振興財団)  4   95-100 1989.10

Research paper (other academic), Joint Work

　View Summary

デンプン及びアミロースの酸化体を合成し、その生分解性と合成洗剤用ビルダー性能の検討を行った。

Organic Builder XX. Building performance and biodegradability of polyelectrolytes

松村秀一、今井一康、前田秀一、吉川貞雄

Proceedings of Session Lectures and Scientific Presentations on ISF-JOCS World Congress 1988  1989.10

Research paper (conference, symposium, etc.), Joint Work

　View Summary

生分解性を有する高分子電解質のビルダー機能について記述した。

Recognition of tetralin hydroperoxide by cyclodextrins

Asakura Kouichi, Tanaka Nobutoshi, Matsumura Shuichi, Yoshikawa Sadao

Chemistry Letters 1989 ( 10 ) 1997-2000 1989.10

Research paper (scientific journal), Joint Work, Accepted

　View Summary

シクロデキストリンがテトラリン過酸化物を選択的に取り込むことを明らかにした。

Antioxidant effect and antimicrobial activity of phenolic sulfides

Asakura Kouichi, Matsumura Shuichi, Yoshikawa Sadao, Kawada Kazuo, Uchibori Tsuyoshi,

Journal of the American Oil Chemists' Society (The American Oil Chemists' Society)  66 ( 10 ) 1450-1453 1989.10

Research paper (scientific journal), Joint Work, Accepted

　View Summary

フェノール性スルフィドを合成し、それらの抗酸化性と抗菌性の測定を行った。

Organic Builders. XXIII. Preparation and builder performance of poly[(sodium acrylate)-co-(2-cyclohexene-1-one)]

Matsumura Shuichi, Maeda Shuichi, Yoshikawa Sadao

Journal of Japan Oil Chemists' Society (日本油化学協会)  38 ( 8 ) 612-618 1989.08

Research paper (scientific journal), Joint Work, Accepted

　View Summary

生分解性を有する新規なポリカルボン酸塩を合成し、合成洗剤用ビルダーとしての機能について検討した。

キチン及びキトサン誘導体の合成と吸・保湿性

Matsumura shuichi, Han Ching Cheng, Minami Masahiro, Yoshikawa Sadao, Kariyone Takao

油化学 (日本油化学協会)  38 ( 6 ) 492-500 1989.06

Research paper (scientific journal), Joint Work, Accepted

　View Summary

キチン及びキトサンのカルボキシル体及びヒドロキシル化物を合成し、吸・保湿性について検討を行った。

メチルα-D- 及び β-D-ガラクトウロン酸の合成

Kuroda Akihiro, Matsumura Shuichi, Yoshikawa Sadao

Chemistry Express 4 ( 3 ) 205-208 1989.03

Research paper (scientific journal), Joint Work, Accepted

　View Summary

白金触媒によるメチルガラクトシドのウロン酸への接触酸化について検討した。

Microbial transformation of poly(ethylene glycol)s into mono- and dicarboxylic derivatives by specific oxidation of the hydroxymethyl groups

Matsumura Shuichi, Yoda Nobuo, Yoshikawa Sadao

Makromoleculare Chemie, Rapid Communications 10 ( 2 ) 63-67 1989.02

Research paper (scientific journal), Joint Work, Accepted

　View Summary

ポリエチレングリコール類の微生物による位置選択的酸化について記した。

Formation of uronic acid by galactose oxidase

Matsumura Shuichi, Kuroda Akihiro, Yoshikawa Sadao

Chemistry Letters 1988 ( 10 ) 1747-1750 1988.10

Research paper (scientific journal), Joint Work, Accepted

　View Summary

ガラクトースオキシダーゼによるメチルガラクトシド及びガラクトース残基を有するオリゴマーのウロン酸への新規な変換反応について検討を行った。

洗剤用ビルダーに関する研究：新規なオリゴ糖系多塩基酸型ビルダー

Matsumura Shuichi, Imai Kazuyasu, Yasaki Yuuichi, Yoshikawa Sadao

化学素材研究振興財団研究報告 (化学素材研究振興財団)  3   59-64 1988.10

Research paper (other academic), Joint Work

　View Summary

オリゴ糖の酸化開裂により得たポリカルボン酸塩の合成洗剤用ビルダー性能及び生分解性の検討を行った。

高分子酸化防止剤の研究（第３報）ポリビニルフェノールについて

Matsumura Shuichi, Kasama Hidenori, Asakura Kouichi

油化学 (日本油化学協会)  37 ( 8 ) 654-658 1988.08

Research paper (scientific journal), Joint Work, Accepted

　View Summary

ポリビニルフェノールのラードに対する酸化防止力とその発現機について検討した。

ポリビニルアルコール及びポリ(ポリビニルオキシ酢酸ナトリウム) の生分解

松村秀一、高橋淳、前田秀一、吉川貞雄

高分子論文集、45(4)  1988.04

Joint Work

　View Summary

ポリ(ポリビニルオキシ酢酸ナトリウム) の生分解性について分解菌の単離を行い検討を行った。

高分子酸化防止剤の研究（第２報）線状及び環状メチレン結合フェノールオリゴマーについて

Asakura Kouichi, Matsumura Shuichi, Yoshikawa Sadao

油化学 (日本油化学協会)  37 ( 4 ) 265-270 1988.04

Research paper (scientific journal), Joint Work, Accepted

　View Summary

線状、環状及びノボラック型の分子構造を有するメチレン結合フェノールオリゴマーを合成しラードに対する酸化防止力とその発現機について検討した。

ポリビニルアルコール及びポリ[(アクリル酸ナトリウム)-co-(ビニルアルコール)] の生分解

Matsumura Shuichi, Maeda Shuichi, Takahashi Jun, Yoshikawa Sadao

高分子論文集 (高分子学会)  45 ( 4 ) 317-324 1988.04

Research paper (conference, symposium, etc.), Joint Work, Accepted

　View Summary

ポリビニルアルコール及びそのコポリマーの生分解性について分解菌の単離を行い検討を行った。

Molecular design of biodegradable functional polymers, 1. Poly(sodium vinyloxyacetate)

Matsumura Shuichi, Takahashi Jun, Maeda Shuichi, Yoshikawa Sadao

Makromoleculare Chemie, Rapid Communications 9 ( 1 ) 1-5 1988.01

Research paper (scientific journal), Joint Work, Accepted

　View Summary

生分解性を有する高分子電解質の分子設計としてポリ（ビニルオキシ酢酸ナトリウム）を合成し、生分解性の検討を行った。

有機ビルダー（第２２報）エーテル結合を含むオリゴマーのビルダー性能と生分解性

Matsumura Shuichi, Hashimoto Katsuo, Yoshikawa Sadao

油化学 (日本油化学協会)  36 ( 11 ) 874-881 1987.11

Research paper (scientific journal), Joint Work, Accepted

　View Summary

主鎖にエーテル結合を含むポリカルボン酸を合成し、合成洗剤用ビルダー性能及び生分解性について検討を行った。

有機ビルダー（第２１報）メチルグルコシド骨格を有するポリカルボン酸

Matsumura Shuichi, Yamanaka Yukiko, Nomoto Kaoru

油化学 (日本油化学協会)  36 ( 1 ) 32-37 1987.01

Research paper (scientific journal), Joint Work, Accepted

　View Summary

メチルグルコシドのカルボキシメトキシル体を合成し、合成洗剤用ビルダー作用及び生分解性について検討を行った。

アクリル酸エステル型オリゴマーの泡消し性について

Abe Yoshiro, Matsumura Shuichi, Kokumai Hirokazu

油化学 (日本油化学協会)  35 ( 12 ) 1025-1030 1986.12

Research paper (scientific journal), Joint Work, Accepted

　View Summary

アクリル酸長鎖アルキルエステル及びアクリル酸ポリオキシエチレンエステル共重合体の泡消し性について検討を行った。

有機ビルダー（第２０報）ポリ（βーリンゴナトリウム）の生分解性とビルダー作用について

Abe Yoshiro, Matsumura Shuichi, Imai Kazuyasu

油化学 (日本油化学協会)  35 ( 11 ) 937-944 1986.11

Research paper (scientific journal), Joint Work, Accepted

　View Summary

ポリ（βーリンゴナトリウム）の合成と合成洗剤用ビルダー作用及び生分解性について検討を行った。

高分子酸化防止剤の研究（第１報）全オルトメチレン結合線状アルキルフェノールオリゴマーについて

Abe Yoshiro, Matsumura Shuichi, Asakura Kouichi, Kasama Hidenori

油化学 (日本油化学協会)  35 ( 9 ) 751-755 1986.09

Research paper (scientific journal), Joint Work, Accepted

　View Summary

全オルトメチレン結合線状アルキルフェノールオリゴマーの抗酸化性について検討を行った。

Enzymatic synthesis of functional oligomers. 1. Lipase catalyzed polymerization of hydroxy acids

Matsumura Shuichi, Takahashi Jun

Makromoleculare Chemie, Rapid Communications 7 ( 3 ) 369-373 1986.06

Research paper (scientific journal), Joint Work, Accepted

　View Summary

リパーゼを用いてヒドロキシ酸を重合させポリエステルを得る新規合成法について報告した。

有機ビルダー（第１９報）ポリカルボン酸型オリゴマーの金属イオン封鎖能とビルダー性能について

Abe Yoshiro, Matsumura Shuichi, Takahashi Jun

油化学 (日本油化学協会)  35 ( 3 ) 167-175 1986.03

Research paper (scientific journal), Joint Work, Accepted

　View Summary

種々のポリカルボン酸型オリゴマーの各種金属イオン封鎖能、ビルダー性能及び生分解性について検討を行った。

有機ビルダー（第１８報）アクリル酸とビニルアルコール、メチレン＝ビニル＝エーテル及び２-ヒドロキシアクリル酸とのコポリマーについて

Abe Yoshiro, Matsumura Shuichi, Sakata Hideaki, Miura Takeshi, Sakai Kaname

油化学 (日本油化学協会)  34 ( 6 ) 456-466 1985.06

Research paper (scientific journal), Joint Work, Accepted

　View Summary

アクリル酸とビニルアルコール、メチレン＝ビニル＝エーテル及び２-ヒドロキシアクリル酸とのコポリマーの合成洗剤用ビルダー性能および生分解性について検討を行った。

有機ビルダー（第１７報）アクリル酸ービニルスルホン酸型コポリマーについて

Abe Yoshiro, Matsumura Shuichi, Masago Yoshikuni, Hashimoto Katsuo, Miura Takeshi, Sakai Kaname

油化学 (日本油化学協会)  34 ( 3 ) 202-205 1985.03

Research paper (scientific journal), Joint Work, Accepted

　View Summary

アクリル酸ービニルスルホン酸型コポリマーの合成洗剤用ビルダー性能について検討を行った。

有機ビルダー（第１６報）オリゴマーの生分解性

Abe Yoshiro, Matsumura Shuichi, Yajima Hatsumi, Suzuki Rentaro, Masago Yoshikuni

油化学 (日本油化学協会)  33 ( 4 ) 228-232 1984.04

Research paper (scientific journal), Joint Work, Accepted

　View Summary

種々のアクリル酸系オリゴマーの生分解性について検討を行った。

有機ビルダー（第１４報）アクリル酸系オリゴマーについて

Abe Yoshiro, Matsumura Shuichi, Suzuki Rentaro, Miura Takeshi, Sakai Kaname

油化学 (日本油化学協会)  33 ( 4 ) 211-218 1984.04

Research paper (scientific journal), Joint Work, Accepted

　View Summary

アクリル酸とメチル＝ベニル＝エーテル、メチル＝ビニル＝スルフィド、2-ヒドロキシアクリル酸などのコポリマーの合成洗剤用ビルダー性能について検討した。

有機ビルダー（第１５報）テロマー型ビルダーについて

Abe Yoshiro, Matsumura Shuichi, Yajima Hatsumi, Masago Yoshikuni, Miura Takeshi, Sakai Kaname

油化学 (日本油化学協会)  33 ( 4 ) 219-227 1984.04

Research paper (scientific journal), Joint Work, Accepted

　View Summary

アクリル酸及びメタクリル酸型テロマーの合成洗剤用ビルダー性能について検討を行った。

The relationship between defoaming power and dynamic surface tension of sodium dodecylbenzene sulfonate solutions with alcohols

Abe Yoshiro, Matsumura Shuichi

Tenside Detergents 20 ( 5 ) 218-224 1983.10

Research paper (scientific journal), Joint Work, Accepted

　View Summary

消泡力と動的表面張力との関係をドデシルベンゼンスルホン酸ナトリウムとアルコールの溶液を用いて検討を行った。

グリコールの泡消し性（第５報）

Abe Yoshiro, Matsumura Shuichi, Matsuda Kouichi

油化学 31 ( 12 ) 1014-1020 1982.12

Research paper (scientific journal), Joint Work, Accepted

　View Summary

長鎖 1,3-アルカンジオールの分子構造と泡消し性の関係について検討を行った。

長鎖１、３型アルカンジオールのあわ消し性（第５報）

Abe Yoshiro, Matsumura Shuichi

旭硝子工業技術奨励会研究報告 41   67-75 1982.10

Research paper (other academic), Joint Work

　View Summary

長鎖 1,3-アルカンジオールの泡消し性について検討を行った。

有機ビルダー（第１３報）ラジカル重合及びアニオン重合により得られたポリ（メタクリル酸ナトリウム）とポリ（フマル酸二ナトリウム）について

Abe Yoshiro, Matsumura Shuichi, Miura Takeshi, Sakai Kaname

油化学 (日本油化学協会)  31 ( 9 ) 586-590 1982.09

Research paper (scientific journal), Joint Work

　View Summary

立体規則性を有するポリ（メタクリル酸ナトリウム）を合成し、立体規則性とビルダー性能の関係を検討した。さらにポリ（フマル酸二ナトリウム）についても研究を行った。

有機ビルダー（第１２報）ポリ（アクリル酸ナトリウム）及びポリ（２-ヒドロキシアクリル酸ナトリウム）について

Abe Yoshiro, Matsumura Shuichi, Miura Takeshi, Sakai Kaname

油化学 30 ( 11 ) 757-761 1981.11

Research paper (scientific journal), Joint Work, Accepted

　View Summary

ポリ（アクリル酸ナトリウム）及びポリ（２-ヒドロキシアクリル酸ナトリウム）のビルダー作用について、分子量との関係について検討を行った。

有機ビルダー（第１１報）マロン酸型エーテルカルボン酸のビルダー効果について

Abe Yoshiro, Matsumura Shuichi, Miura Takeshi, Sakai Kaname

油化学 (日本油化学協会)  30 ( 1 ) 31-37 1981.01

Research paper (scientific journal), Joint Work, Accepted

　View Summary

分子内にエーテル結合を有するマロン酸型エーテルカルボン酸の合成洗剤用ビルダー性能について検討を行った。

有機ビルダー（第１０報）エーテル結合をもつカルボン酸型ビルダーの物理化学性（その３）

Abe Yoshiro, Matsumura Shuichi

油化学 (日本油化学協会)  29 ( 10 ) 748-754 1980.10

Research paper (scientific journal), Single Work, Accepted

　View Summary

一連のポリカルボン酸のキレート力や分散力と分子構造との関係について検討を行った。

有機ビルダーに関する研究

Matsumura Shuichi

油化学 (日本油化学協会)  29 ( 10 ) 728-734 1980.10

Research paper (scientific journal), Single Work

　View Summary

合成洗剤用有機ビルダーの研究について主として著者の研究を記した。

グリコールのあわ消し性（第４報）

Abe Yoshiro, Matsumura Shuichi, Tsai Bei Tsang

油化学 (日本油化学協会)  29 ( 3 ) 181-188 1980.03

Research paper (scientific journal), Joint Work, Accepted

　View Summary

長鎖アルカンジオールのあわ消し性について測定した。

グリコールのあわ消し性（第３報）エチレンオキシドならびにプロピレンオキシド付加体について

Abe Yoshiro, Matsumura Shuichi

油化学 (日本油化学協会)  28 ( 11 ) 842-846 1979.11

Research paper (scientific journal), Joint Work, Accepted

　View Summary

アルカンンジオールのエチレンオキシド又はプロピレンオキシド付加体のあわ消し性について測定した。

有機ビルダー（第９報）トリポリリン酸ナトリウムーキレート型ポリカルボン酸塩混合物のビルダー作用

Matsumura Shuichi

油化学 (日本油化学協会)  28 ( 6 ) 403-406 1979.06

Research paper (scientific journal), Single Work, Accepted

　View Summary

トリポリリン酸ナトリウムーキレート型ポリカルボン酸塩の二成分混合物の合成洗剤用ビルダー性能について検討を行った。

グリコールのあわ消し性（第２報）

Abe Yoshiro, Matsumura Shuichi, Shibuya Yukihiro

油化学 (日本油化学協会)  28 ( 4 ) 276-284 1979.04

Research paper (scientific journal), Joint Work, Accepted

　View Summary

アルカンジオールのあわ消し性について検討を行った。

有機ビルダー（第８報）エーテル結合をもつカルボン酸型ビルダーの物理化学性（その２）

Abe Yoshiro, Matsumura Shuichi

油化学 (日本油化学協会)  27 ( 11 ) 785-792 1978.11

Research paper (scientific journal), Joint Work, Accepted

　View Summary

分子内にエーテル結合を含む多塩基酸のキレート力、分散力などについて測定を行った。

有機ビルダー（第７報）キレート型ポリカルボン酸のビルダー効果に対する置換基の影響

Abe Yoshiro, Matsumura Shuichi, Miura Takeshi, Sakai Kaname

油化学 (日本油化学協会)  27 ( 11 ) 778-784 1978.11

Research paper (scientific journal), Joint Work, Accepted

　View Summary

各種置換基を有するポリカルボン酸を合成し合成洗剤用ビルダー性能の評価を行った。

エーテル結合を含む二塩基酸（第７報）ビルダー作用（その５）グリセリンおよびそのオリゴマーの多塩基酸

Abe Yoshiro, Matsumura Shuichi, Miura Takeshi, Mochizuki Atsushi

油化学 (日本油化学協会)  26 ( 8 ) 458-463 1977.08

Research paper (scientific journal), Joint Work, Accepted

　View Summary

エーテル結合を含む二塩基酸と多塩基酸の洗浄力を比較した。

１-オレフィン二量体より得られたグリコールのあわ消し性

Abe Yoshiro, Matsumura Shuichi

油化学 (日本油化学協会)  26 ( 7 ) 470-473 1977.08

Research paper (scientific journal), Joint Work, Accepted

　View Summary

１-オレフィンを二量化し、過酸でジヒドロキシル化を行い 1,2-ジオールを得、そのあわ消し性を測定した。

カルボン酸型ビルダー溶液の物理化学性

Abe Yoshiro, Matsumura Shuichi

油化学 (日本油化学協会)  26 ( 7 ) 416-425 1977.07

Research paper (scientific journal), Joint Work, Accepted

　View Summary

種々のエーテル結合を含む多塩基酸の金属イオンキレート力、分散力などの溶液物性について測定した。

エーテル結合を含む二塩基酸（第６報）ビルダー作用（その４）エーテル結合を含む二塩基酸と三塩基酸および四塩基酸との比較

Abe Yoshiro, Matsumura Shuichi, Miura Takeshi, Mochizuki Atsushi

油化学 (日本油化学協会)  25 ( 9 ) 541-545 1976.09

Research paper (scientific journal), Joint Work, Accepted

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エーテル結合を含む二塩基酸と三塩基酸および四塩基酸のビルダー作用について比較検討を行った。

エーテル結合を含む二塩基酸（第５報）ビルダー作用（その３）オキサモノカルボン酸およびオキサトリカルボン酸との比較

Abe Yoshiro, Matsumura Shuichi, Miura Takeshi, Mochizuki Atsushi

油化学 (日本油化学協会)  24 ( 7 ) 456-463 1975.07

Research paper (scientific journal), Joint Work, Accepted

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エーテルモノカルボン酸およびエーテルトリカルボン酸エーテルジカルボン酸のビルダー性能について比較検討を行った。

エーテル結合を含む二塩基酸（第４報）ビルダー作用（その２）オキサ、アザ、チア、ヒドラジノおよび２-オキシエチルイミノジカルボン酸について

Abe Yoshiro, Matsumura Shuichi, shirahata Takashi, Miura Takashi, Mochizuki Atsushi

油化学 (日本油化学協会)  ２４ ( １ ) 31-35 1975.01

Research paper (scientific journal), Joint Work, Accepted

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分子内にエーテル結合を含むものとチオエーテル又はイミノ結合を含むものを合成し、洗剤用ビルダー性能について比較を行った。

エーテル結合を含む二塩基酸（第３報）ビルダー作用について

Abe Yoshiro, Matsumura Shuichi, Iino Shinnji, Miura Takeshi, Mochizuki Atsushi

油化学 (日本油化学協会)  23 ( 5 ) 316-320 1974.05

Research paper (scientific journal), Joint Work, Accepted

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分子内にエーテル結合を含む二塩基酸を合成し、合成洗剤用ビルダー性能について検討した。

Long chain carboxylic acids containing ether linkage: IV. The antibacterial activities of O-(2-alkylaminoethyl)-3-oxypropionic and N-(2-alkyloxyethyl)-3-aminopropionic acids

Abe Yoshiro, Osanai Shuichi, Matsumura Shuichi

Journal of the American Oil Chemists' Society (The American Oil Chemists' Society)  49 ( 6 ) 357-360 1972.06

Research paper (scientific journal), Joint Work, Accepted

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分子内にエーテル結合を含む両性界面活性剤を合成し物性の測定を行った。