Reviews, Commentaries, etc. - Takahashi, Daisuke

高機能性化粧品素材の創製を指向したマンノシルエリスリトールリピッド（MEL）類縁体の合成と構造活性相関研究

孟継坤, *戸嶋一敦, *高橋大介

オレオサイエンス 24 ( 11 ) 475 - 481 2024.11

Article, review, commentary, editorial, etc. (scientific journal), Joint Work, Last author, Corresponding author

• Access to Document (DOI)

ホウ素媒介アグリコン転移反応の新展開:反応開発,有用糖質合成,およびケミカルバイオロジーへの応用

*高橋大介, *戸嶋一敦

有機合成化学協会誌 82 ( 9 ) 856 - 866 2024.09

Article, review, commentary, editorial, etc. (scientific journal), Joint Work, Lead author, Corresponding author

Total Synthesis of Mannosylerythritol Lipids and Structure-Function Relationship Studies

*DAISUKE TAKAHASHI, Kazunobu Toshima

Journal of Oleo Science 73 ( 4 ) 539 - 546 2024.04

Article, review, commentary, editorial, etc. (scientific journal), Joint Work, Lead author, Corresponding author

Photo-Induced Glycosylations Using Organophotoacids: A New Environmentally Benign Carbohydrate Synthesis

*Kazunobu Toshima, DAISUKE TAKAHASHI, Yuka Isozaki

Synlett 35   777 - 788 2023.07

Article, review, commentary, editorial, etc. (scientific journal), Joint Work

有機化学を基盤とした鳥類病原性大腸菌に対する複合糖質ワクチン開発への挑戦

<u>高橋大介</u>

日生研たより 69 ( 2 ) 3 - 11 2023.04

Article, review, commentary, editorial, etc. (scientific journal), Single Work, Lead author, Last author, Corresponding author

Boron-mediated aglycon delivery (BMAD) for the stereoselective synthesis of 1,2-cis glycosides

*DAISUKE TAKAHASHI, Kazunobu Toshima

Advances in Carbohydrate Chemistry and Biochemistry 82   79 - 105 2022.11

Article, review, commentary, editorial, etc. (scientific journal), Joint Work, Lead author, Corresponding author

• Access to Document (DOI)

Recent advances in boron-mediated aglycon delivery (BMAD) for the efficient synthesis of 1,2-cis glycosides

*DAISUKE TAKAHASHI, Kazuki Inaba, *Kazunobu Toshima

Carbohydrate Research (Carbohydrate Research)  518   108579 2022.08

Joint Work, Lead author, Corresponding author,  ISSN  00086215

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Highly stereoselective synthesis of 1,2-cis glycosides remains a challenging task due to the lack of reliable neighboring group participation (NGP) from the 2-O-acyl functionality in the glycosyl donor. In this context, our group recently developed highly 1,2-cis-stereoselective glycosylation methods, named boron-mediated aglycon delivery (BMAD), using organoboron reagents and 1,2-anhydroglycosyl donors. In this mini-review article, we introduce the BMAD methods and their applications to the synthesis of biologically active natural products and complex glycosides reported since our mini-review article published in this journal in 2017.

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Photo-induced Glycosylation Using Organophotoacids

*Kazunobu Toshima;DAISUKE TAKAHASHI

Bioindustry (シーエムシー出版)  38 ( 8 ) 3 - 11 2021.08

Article, review, commentary, editorial, etc. (scientific journal), Joint Work, Last author

Boron-Mediated Aglycon Delivery and Application to the Synthesis of Pathogenic Bacterial Oligosaccharides

*DAISUKE TAKAHASHI;*Kazunobu Toshima

Bioindustry (シーエムシー出版)  38 ( 8 ) 32 - 41 2021.08

Article, review, commentary, editorial, etc. (scientific journal), Joint Work, Lead author, Corresponding author

【ディビジョン・トピックス】化学合成を駆使したワクチン開発への挑戦

*DAISUKE TAKAHASHI

化学と工業 74   513 - 513 2021.06

Single Work, Lead author, Last author, Corresponding author

マンノシルエリスリトールリピッド（MEL）の効率的全合成と抗菌活性を指標とした構造－機能相関の解明

*高橋大介, *戸嶋一敦

オレオサイエンス 20 ( 5 ) 209 - 214 2020.05

Article, review, commentary, editorial, etc. (scientific journal), Joint Work

• Access to Document (DOI)

Development and Application of Boronic-Acid-Catalyzed Regioselective and 1,2-cis-Stereoselective Glycosylation

*DAISUKE TAKAHASHI

Journal of Synthetic Organic Chemistry, Japan 78 ( 3 ) 221 - 231 2020.03

Article, review, commentary, editorial, etc. (scientific journal), Single Work, Lead author, Last author, Corresponding author

• Access to Document (DOI)

架橋構造をもつ糖

高橋大介, 戸嶋一敦

月刊化学 75 ( 2 ) 72 - 73 2020.01

Article, review, commentary, editorial, etc. (scientific journal), Joint Work

Boronic-acid-catalyzed regioselective and stereoselective glycosylations via S_Ni-type mechanism

*DAISUKE TAKAHASHI

TRENDS IN GLYCOSCIENCE AND GLYCOTECHNOLOGY 31 ( 181 ) SE93 - SE94 2019.07

Article, review, commentary, editorial, etc. (scientific journal), Single Work, Lead author, Last author, Corresponding author,  ISSN  09157352

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© 2018 FCCA (Forum: Carbohydrates Coming of Age) Development of regio- and stereoselective glycosylations leading to a specific hydroxyl group among several free hydroxyl groups is a challenging and long-standing research subject in carbohydrate chemistry. In this context, several efficient regio- and stereoselective glycosylation methods utilizing organoboron reagents, which can bind reversibly to cis-1,2- or 1,3-diols under mild conditions, have been reported. In this focused review article, several organoboron-mediated regio- and stereoselective glycosylations are described, including recently developed methods.

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Target-Selective Photodegradation of Glycoprotein Using an Anthraquinone－Lectin Hybrid

*DAISUKE TAKAHASHI;*Kazunobu Toshima

週刊医学のあゆみ ( 医歯薬出版)  269 ( 9 ) 711 - 717 2019.06

Article, review, commentary, editorial, etc. (scientific journal), Joint Work, Lead author, Corresponding author

Regioselective and Stereoselective Glycosylations Utilizing Organoboron Compounds

*DAISUKE TAKAHASHI, Masamichi Tanaka, *Kazunobu Toshima

TRENDS IN GLYCOSCIENCE AND GLYCOTECHNOLOGY (Trends in Glycoscience and Glycotechnology)  30 ( 174 ) E55 - E62 2018.05

Article, review, commentary, editorial, etc. (scientific journal), Single Work, Lead author, Corresponding author,  ISSN  09157352

　View Summary

© 2018 FCCA (Forum: Carbohydrates Coming of Age) Development of regio- and stereoselective glycosylations leading to a specific hydroxyl group among several free hydroxyl groups is a challenging and long-standing research subject in carbohydrate chemistry. In this context, several efficient regio- and stereoselective glycosylation methods utilizing organoboron reagents, which can bind reversibly to cis-1,2- or 1,3-diols under mild conditions, have been reported. In this focused review article, several organoboron-mediated regio- and stereoselective glycosylations are described, including recently developed methods.

• Access to Document (DOI)

Borinic Acid Catalyzed 1,2─cis─Stereoselective Glycosylations and Their Applications to the Total Synthesis of Natural Products

*Daisuke Takahashi

Journal of Synthetic Organic Chemistry, Japan (The Society of Synthetic Organic Chemistry, Japan)  76 ( 5 ) 470 - 473 2018.05

Article, review, commentary, editorial, etc. (scientific journal), Single Work, Lead author, Last author, Corresponding author

• Access to Document (DOI)

Novel 1,2-cis-Stereoselective Glycosylations Utilizing Organoboron Reagents and Their Application to Natural Products and Complex Oligosaccharide Synthesis

*DAISUKE TAKAHASHI, Masamichi Tanaka, Nobuya Nishi, *Kazunobu Toshima

CARBOHYDRATE RESEARCH (Elsevier)  452 ( 27 ) 64 - 77 2017.10

Article, review, commentary, editorial, etc. (scientific journal), Joint Work, Lead author, Corresponding author,  ISSN  0008-6215

• Access to Document (DOI)

Direct and stereoselective synthesis of β-mannosides by anomeric O-alkylation

*Daisuke Takahashi

TRENDS IN GLYCOSCIENCE AND GLYCOTECHNOLOGY 28 ( 164 ) E119 - E120 2016.11

Article, review, commentary, editorial, etc. (scientific journal), Single Work,  ISSN  0915-7352

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【飛翔する若手研究者】　有機ホウ素化合物を利用した標的糖鎖の選択的合成と光分解

*DAISUKE TAKAHASHI

CHEMISTRY & CHEMICAL INDUSTRY (The Chemical Society of Japan)  69 ( 10 ) 881 - 882 2016.10

Article, review, commentary, editorial, etc. (scientific journal), Single Work, Lead author, Last author, Corresponding author